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- W2018183721 endingPage "4884" @default.
- W2018183721 startingPage "4861" @default.
- W2018183721 abstract "Over the past 40 years, much of my research has evolved around various topics of conformational analysis and asymmetric synthesis. This Perspective describes some of my salient contributions in eight different areas of organic stereochemistry: (1) conformational analysis of six-membered rings, (2) evaluation of stereoelectronic interactions in (1)J(C-H) one-bond coupling constants in six-membered rings, (3) eclipsed conformation in cis-2-tert-butyl-5-(tert-butylsulfonyl)-1,3-dioxane, (4) determination of enthalpic and entropic contributions to ΔG°(CH(2)Ph) and ΔG°(t-Bu), (5) study of the attractive gauche effect in O-C-C-O segments, (6) examination of salt effects on conformational equilibria, (7) asymmetric synthesis of β-amino acids, and (8) asymmetric organocatalysis and Green chemistry. It will be appreciated that a basic understanding of the principles of physical organic chemistry has been essential in all projects. Furthermore, curiosity, enthusiasm, obstinacy, and paying attention to unexpected observations will lead to many new (stereo)chemical discoveries." @default.
- W2018183721 created "2016-06-24" @default.
- W2018183721 creator A5073766594 @default.
- W2018183721 date "2012-04-04" @default.
- W2018183721 modified "2023-09-27" @default.
- W2018183721 title "Looking for Treasure in Stereochemistry-Land. A Path Marked by Curiosity, Obstinacy, and Serendipity" @default.
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