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- W2018192170 abstract "The kinetics of oxidation of amino acids in aqueous medium were reinvestigated. The rate of oxidation follows second order with respect to chloramine-T (CAT) and an inverse dependence on [p-toluene-sulfonamide] (RNH2). At constant [RNH2] the rate of the reaction can be represented as (in the absence of chloride ion) frac−d[CAT]dt=ka[CAT]2+kbfrac[Amino Acid][CAT]2[H+]+kcfrac[Amino Acid]2[CAT]2[H+]2. A linear relationship exists between pK1 and the rate constants. This shows the electrophilic attack of the oxidant at the carboxylato group of the amino acid. The effect of chloride ion on kobsd is catalytic. The mechanisms of the reactions are discussed in terms of the kinetic results." @default.
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- W2018192170 date "1987-09-01" @default.
- W2018192170 modified "2023-09-26" @default.
- W2018192170 title "Kinetics of Oxidation of Amino Acids by Chloramine-T. A Reinvestigation on the Oxidation of Alanine, 2-Aminobutyric Acid, Valine, Serine, and Threonine" @default.
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- W2018192170 doi "https://doi.org/10.1246/bcsj.60.3397" @default.
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