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- W2018199904 endingPage "49" @default.
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- W2018199904 abstract "A divalent cobalt iodine complex bearing 1,3-bis(mesityl)imidazol-2-ylidene and pyridine ligands was synthesized and its structure was determined. The cobalt center has a typical d7-tetrahedral geometry, as expected. Catalytic application of this cobalt complex with bromoalkanes and Grignard reagents demonstrated high-yield formation of alkenes as a result of β-hydrogen elimination; in sharp contrast, the activation of alkyl halides was not successful using the larger N-heterocyclic carbene ligand, 1,3-bis(2,6-diisopropyl-phenyl)imidazol-2-ylidene. In the presence of styrene, Heck reaction proceeded with trans selectivity. The reaction of a substrate containing a bromobenzyl moiety yielded a homocoupling product." @default.
- W2018199904 created "2016-06-24" @default.
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- W2018199904 date "2013-03-01" @default.
- W2018199904 modified "2023-09-26" @default.
- W2018199904 title "Synthesis and structure of cobalt(II) iodide bearing a bulky N-heterocyclic carbene ligand, and catalytic activation of bromoalkanes" @default.
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- W2018199904 doi "https://doi.org/10.1016/j.jorganchem.2012.12.025" @default.
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