Matches in SemOpenAlex for { <https://semopenalex.org/work/W2018220557> ?p ?o ?g. }
Showing items 1 to 91 of
91
with 100 items per page.
- W2018220557 endingPage "98" @default.
- W2018220557 startingPage "91" @default.
- W2018220557 abstract "The reaction between [(R-DAB)Rh(PR 3 ) 2 ] + and molecular hydrogen produces cationic cis -dihydride complexes of Rh(III), of general formula [RhH 2 (R-DAB)(PR 3 ) 2 ]X. They are stable in air, 1:1 conductors and have been characterized by 1 H NMR, 31 P NMR, IR and elemental analysis. The tertiary phosphines employed were: PPh 3 , P( p -C 6 H 4 F) 3 , PMePh 2 , PEt 3 , and the R-DAB ligands (RN:CR′CR′:NR) 1 1 Herein they will be referred to as R-DAB when they are derivatives of glioxal or as R-DAB(CH 3 ,CH 3 ) when they are derived from diacetyl. , Ph-DAB, c-Hex-DAB, NH 2 -DAB(CH 3 ,CH 3 ), t-but-DAB. The structure of [RhH 2 (c-Hex-DAB){P( p -C 6 H 4 F) 3 } 2 ]ClO 4 has been determined by an X-ray diffraction study. Crystals are orthorhombic, space group Pbnm . Unit cell parameters are: a = 13.032(1), b = 18.166(2), c = 21.449(2) Å, Z = 4, R = 0.081, R w = 0.082 for 2906 reflections, with I > 3σ( I ) the rhodium atom is octahedrally coordinated with the two hydride-hydrogens and c-Hex-DAB in the equatorial plane; the two phosphine ligands are in an axial position bent towards the hydrogens making an angle of 164.9(4)°." @default.
- W2018220557 created "2016-06-24" @default.
- W2018220557 creator A5029820959 @default.
- W2018220557 creator A5039835792 @default.
- W2018220557 creator A5062278402 @default.
- W2018220557 creator A5062350437 @default.
- W2018220557 creator A5076741533 @default.
- W2018220557 date "1988-05-01" @default.
- W2018220557 modified "2023-10-16" @default.
- W2018220557 title "Synthesis, characterization and structure of cationic hydrides of rhodium(III). Part II. Crystal structure of dihydride(1,4-biscyclohexyl-diaza-1,3-butadiene)-bis(4-fluor-tristriphenylphosphine)rhodium(III) perchlorate" @default.
- W2018220557 cites W1574228204 @default.
- W2018220557 cites W1889685237 @default.
- W2018220557 cites W1968331067 @default.
- W2018220557 cites W1982037693 @default.
- W2018220557 cites W2003450032 @default.
- W2018220557 cites W2004925864 @default.
- W2018220557 cites W2050288169 @default.
- W2018220557 cites W2072908155 @default.
- W2018220557 cites W2078753530 @default.
- W2018220557 cites W2101748147 @default.
- W2018220557 cites W4231952765 @default.
- W2018220557 doi "https://doi.org/10.1016/s0020-1693(00)82013-7" @default.
- W2018220557 hasPublicationYear "1988" @default.
- W2018220557 type Work @default.
- W2018220557 sameAs 2018220557 @default.
- W2018220557 citedByCount "8" @default.
- W2018220557 countsByYear W20182205572012 @default.
- W2018220557 countsByYear W20182205572018 @default.
- W2018220557 crossrefType "journal-article" @default.
- W2018220557 hasAuthorship W2018220557A5029820959 @default.
- W2018220557 hasAuthorship W2018220557A5039835792 @default.
- W2018220557 hasAuthorship W2018220557A5062278402 @default.
- W2018220557 hasAuthorship W2018220557A5062350437 @default.
- W2018220557 hasAuthorship W2018220557A5076741533 @default.
- W2018220557 hasConcept C115624301 @default.
- W2018220557 hasConcept C145148216 @default.
- W2018220557 hasConcept C155647269 @default.
- W2018220557 hasConcept C161790260 @default.
- W2018220557 hasConcept C178790620 @default.
- W2018220557 hasConcept C183882617 @default.
- W2018220557 hasConcept C185592680 @default.
- W2018220557 hasConcept C188027245 @default.
- W2018220557 hasConcept C2777247709 @default.
- W2018220557 hasConcept C2777716191 @default.
- W2018220557 hasConcept C2777961443 @default.
- W2018220557 hasConcept C2780709120 @default.
- W2018220557 hasConcept C37243968 @default.
- W2018220557 hasConcept C512968161 @default.
- W2018220557 hasConcept C521398313 @default.
- W2018220557 hasConcept C55493867 @default.
- W2018220557 hasConcept C71240020 @default.
- W2018220557 hasConcept C8010536 @default.
- W2018220557 hasConceptScore W2018220557C115624301 @default.
- W2018220557 hasConceptScore W2018220557C145148216 @default.
- W2018220557 hasConceptScore W2018220557C155647269 @default.
- W2018220557 hasConceptScore W2018220557C161790260 @default.
- W2018220557 hasConceptScore W2018220557C178790620 @default.
- W2018220557 hasConceptScore W2018220557C183882617 @default.
- W2018220557 hasConceptScore W2018220557C185592680 @default.
- W2018220557 hasConceptScore W2018220557C188027245 @default.
- W2018220557 hasConceptScore W2018220557C2777247709 @default.
- W2018220557 hasConceptScore W2018220557C2777716191 @default.
- W2018220557 hasConceptScore W2018220557C2777961443 @default.
- W2018220557 hasConceptScore W2018220557C2780709120 @default.
- W2018220557 hasConceptScore W2018220557C37243968 @default.
- W2018220557 hasConceptScore W2018220557C512968161 @default.
- W2018220557 hasConceptScore W2018220557C521398313 @default.
- W2018220557 hasConceptScore W2018220557C55493867 @default.
- W2018220557 hasConceptScore W2018220557C71240020 @default.
- W2018220557 hasConceptScore W2018220557C8010536 @default.
- W2018220557 hasIssue "1" @default.
- W2018220557 hasLocation W20182205571 @default.
- W2018220557 hasOpenAccess W2018220557 @default.
- W2018220557 hasPrimaryLocation W20182205571 @default.
- W2018220557 hasRelatedWork W2002979553 @default.
- W2018220557 hasRelatedWork W2012945066 @default.
- W2018220557 hasRelatedWork W2016446244 @default.
- W2018220557 hasRelatedWork W2054637493 @default.
- W2018220557 hasRelatedWork W2064369770 @default.
- W2018220557 hasRelatedWork W2077281894 @default.
- W2018220557 hasRelatedWork W2079334440 @default.
- W2018220557 hasRelatedWork W2466467356 @default.
- W2018220557 hasRelatedWork W2467623744 @default.
- W2018220557 hasRelatedWork W2949769851 @default.
- W2018220557 hasVolume "145" @default.
- W2018220557 isParatext "false" @default.
- W2018220557 isRetracted "false" @default.
- W2018220557 magId "2018220557" @default.
- W2018220557 workType "article" @default.