Matches in SemOpenAlex for { <https://semopenalex.org/work/W2018221092> ?p ?o ?g. }
- W2018221092 endingPage "5698" @default.
- W2018221092 startingPage "5690" @default.
- W2018221092 abstract "Reaction of lithium enolates of simple ketones with (+/-)-phenyl vinyl sulfoxide has potential for the convergent construction of complex fused ring systems containing a bicyclo[n.2.0]alkan-1-ol. The formation of sulfinylbicyclo[4.2.0]octan-1-ols 1-3 from the lithium enolate of cyclohexanone with (+/-)-phenyl vinyl sulfoxide or (R)-(+)-p-tolyl vinyl sulfoxide 18 was used to probe the mode of this novel cyclization reaction. Using phenyl vinyl sulfoxide, variations in the reaction lighting and solvent were investigated, in conjunction with radical trapping (TEMPO) and isotope labeling (deuterium) experiments. Cyclization to form sulfinylbicyclooctanols 1-3 is likely to proceed via an intermediate that ring closes to the bicycloalkanol anion 11 and was presently favored by the use of solvents such as THF or DME." @default.
- W2018221092 created "2016-06-24" @default.
- W2018221092 creator A5019102977 @default.
- W2018221092 creator A5029483873 @default.
- W2018221092 creator A5088014763 @default.
- W2018221092 date "2004-07-27" @default.
- W2018221092 modified "2023-09-23" @default.
- W2018221092 title "Probing the Formation of Bicyclo[4.2.0]octan-1-ols" @default.
- W2018221092 cites W1506869291 @default.
- W2018221092 cites W1618884619 @default.
- W2018221092 cites W1944470512 @default.
- W2018221092 cites W1964332579 @default.
- W2018221092 cites W1965604579 @default.
- W2018221092 cites W1967497935 @default.
- W2018221092 cites W1971245975 @default.
- W2018221092 cites W1971424232 @default.
- W2018221092 cites W1972993577 @default.
- W2018221092 cites W1974105392 @default.
- W2018221092 cites W1974954984 @default.
- W2018221092 cites W1975522238 @default.
- W2018221092 cites W1987828585 @default.
- W2018221092 cites W1991105069 @default.
- W2018221092 cites W1992143447 @default.
- W2018221092 cites W1996015605 @default.
- W2018221092 cites W1998967167 @default.
- W2018221092 cites W1999006840 @default.
- W2018221092 cites W2000455697 @default.
- W2018221092 cites W2011964543 @default.
- W2018221092 cites W2017003581 @default.
- W2018221092 cites W2021533528 @default.
- W2018221092 cites W2023727309 @default.
- W2018221092 cites W2025771194 @default.
- W2018221092 cites W2027566571 @default.
- W2018221092 cites W2030257338 @default.
- W2018221092 cites W2030846573 @default.
- W2018221092 cites W2037701936 @default.
- W2018221092 cites W2039709640 @default.
- W2018221092 cites W2049295882 @default.
- W2018221092 cites W2049336932 @default.
- W2018221092 cites W2049392271 @default.
- W2018221092 cites W2049556235 @default.
- W2018221092 cites W2060481860 @default.
- W2018221092 cites W2060970925 @default.
- W2018221092 cites W2061164912 @default.
- W2018221092 cites W2066584710 @default.
- W2018221092 cites W2072444524 @default.
- W2018221092 cites W2072453679 @default.
- W2018221092 cites W2075006730 @default.
- W2018221092 cites W2076167992 @default.
- W2018221092 cites W2077713596 @default.
- W2018221092 cites W2079051677 @default.
- W2018221092 cites W2084493153 @default.
- W2018221092 cites W2085199020 @default.
- W2018221092 cites W2094021178 @default.
- W2018221092 cites W2098521829 @default.
- W2018221092 cites W2100626074 @default.
- W2018221092 cites W2110864993 @default.
- W2018221092 cites W2134661541 @default.
- W2018221092 cites W2136929423 @default.
- W2018221092 cites W2169838656 @default.
- W2018221092 cites W2177657295 @default.
- W2018221092 cites W2951375534 @default.
- W2018221092 cites W2952003850 @default.
- W2018221092 cites W2952208927 @default.
- W2018221092 cites W3004618625 @default.
- W2018221092 cites W3021608013 @default.
- W2018221092 doi "https://doi.org/10.1021/jo049576n" @default.
- W2018221092 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/15307741" @default.
- W2018221092 hasPublicationYear "2004" @default.
- W2018221092 type Work @default.
- W2018221092 sameAs 2018221092 @default.
- W2018221092 citedByCount "4" @default.
- W2018221092 crossrefType "journal-article" @default.
- W2018221092 hasAuthorship W2018221092A5019102977 @default.
- W2018221092 hasAuthorship W2018221092A5029483873 @default.
- W2018221092 hasAuthorship W2018221092A5088014763 @default.
- W2018221092 hasConcept C121332964 @default.
- W2018221092 hasConcept C134018914 @default.
- W2018221092 hasConcept C155647269 @default.
- W2018221092 hasConcept C161790260 @default.
- W2018221092 hasConcept C178790620 @default.
- W2018221092 hasConcept C185592680 @default.
- W2018221092 hasConcept C24961977 @default.
- W2018221092 hasConcept C2776701986 @default.
- W2018221092 hasConcept C2778448320 @default.
- W2018221092 hasConcept C2778541603 @default.
- W2018221092 hasConcept C2780378348 @default.
- W2018221092 hasConcept C2780450521 @default.
- W2018221092 hasConcept C2780471494 @default.
- W2018221092 hasConcept C58364064 @default.
- W2018221092 hasConcept C62520636 @default.
- W2018221092 hasConcept C71924100 @default.
- W2018221092 hasConcept C75473681 @default.
- W2018221092 hasConceptScore W2018221092C121332964 @default.
- W2018221092 hasConceptScore W2018221092C134018914 @default.
- W2018221092 hasConceptScore W2018221092C155647269 @default.
- W2018221092 hasConceptScore W2018221092C161790260 @default.
- W2018221092 hasConceptScore W2018221092C178790620 @default.