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- W2018260079 abstract "The crystallographic structure of the complex formed by β-cyclodextrin with 1,10-phenanthroline has been studied by X-ray diffraction. The result shows that the complex adopts an uncommon 2:3 stoichiometry in solid state, that is, every complex unit contains three 1,10-phenanthroline molecules and two β-cyclodextrin molecules, where two 1,10-phenanthroline molecules individually occupy two cyclodextrin cavities, and the third guest molecule is located in the interstitial space between two head-to-head cyclodextrin molecules. The intermolecular hydrogen bonds between the adjacent complex units further link these individual monomers to a channel-type assembly. Furthermore, 1H and 2D NMR spectroscopy has been employed to investigate the inclusion behavior between the host β-cyclodextrin and guest 1,10-phenanthroline in aqueous solution." @default.
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- W2018260079 date "2004-06-01" @default.
- W2018260079 modified "2023-10-10" @default.
- W2018260079 title "Interaction between β-cyclodextrin and 1,10-phenanthroline: uncommon 2:3 inclusion complex in the solid state" @default.
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- W2018260079 doi "https://doi.org/10.1016/j.carres.2004.04.004" @default.
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