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- W2018278312 abstract "Electron paramagnetic resonance studies of the lowest triplet states of adenine (Ade), 2′-deoxyadenosine (dAdo), 2′-deoxyadenosine-5′-monophosphate (dAMP) and 2′-deoxyadenylyl-(3′,5′)-2′-deoxyadenosine (dApdA) in aqueous 12 M LiCl glasses at 77 K were performed. The triplet decay lifetimes of Ade, dAdo and dApdA are 2.9 s, 2.8 s and 2.9 s respectively, while the r.m.s. zero-field splitting parameter D* is 0.133 cm−1 for Ade and dAdo and 0.134 cm−1 for dAMP and dApdA. The intersystem crossing quantum yields for the neutral molecules are 0.17, 0.051, 0.008 and 0.014 for Ade, dAdo, dAMP and dApdA respectively. The rates of intersystem crossing are lower for the cationic or anionic species of these adenine derivatives than for the neutral species." @default.
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- W2018278312 date "1986-04-01" @default.
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- W2018278312 title "An electron paramagnetic resonance study of the excited triplet states of adenine and some of its derivatives in aqueous glasses at 77 K" @default.
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- W2018278312 doi "https://doi.org/10.1016/0047-2670(86)87022-8" @default.
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