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- W2018290412 abstract "We report the discovery of finite length scale effects on vibronic coupling in nanoscale α-Fe2O3 as measured by the behavior of vibronically activated d-d on-site excitations of Fe3+ as a function of size and shape. An oscillator strength analysis reveals that the frequency of the coupled symmetry-breaking phonon changes with size, a crossover that we analyze in terms of increasing three-dimensional character to the displacement pattern. These findings demonstrate the flexibility of mixing processes in confined systems and suggest a strategy for both enhancing and controlling charge-lattice interactions in other materials." @default.
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- W2018290412 date "2014-07-28" @default.
- W2018290412 modified "2023-10-17" @default.
- W2018290412 title "Size-dependent vibronic coupling in α-Fe<sub>2</sub>O<sub>3</sub>" @default.
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- W2018290412 doi "https://doi.org/10.1063/1.4887359" @default.
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