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- W2018335280 abstract "Dipole moments of nickel(II), palladium(II) and cobalt(III) complexes of six new monothio-β-diketones R1C(SH) = CHCOR2 (R1 = phenyl, 2′-naphthyl and 2′-thienyl; R2 = C2F5 and CF2CF2CF3) were determined by static-polarization measurements. With same R2 the dipole moments varies when R1 arranged as 2′-thienyl > 2′-naphthyl > phenyl. With same R1 the dipole moments varies as C3F7 > C2F5. The latter values are small: 0.03–0.37 D for the nickel, 0.08–0.24 D for the palladium and 0.12–0.16 D for the cobalt complexes. Nickel(II) and palladium(II) complexes definitely have cis-square-planar structures Cobalt(III) complexes perhaps have the facial-octahedral configurations." @default.
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- W2018335280 date "1981-01-01" @default.
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- W2018335280 title "Dipole moments of some metal complexes of six new monothio-β-diketones containing perfluoroalkyl group" @default.
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- W2018335280 doi "https://doi.org/10.1016/s0020-1693(00)90061-6" @default.
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