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- W2018337584 abstract "1,1-Dimethyl-3-(phenylthio)-propane 4 was deprotonated with t-BuLi, then converted to the corresponding organocuprate reagent which, in the presence of HMPA and TMSCl, was added to a variety of enones to give the corresponding silylenol ethers 7. These were cyclised without purification upon acidic conditions to give the cyclopentannulation products 9. A similar result was obtained with the corresponding orthoester reagent 6. This cyclopentannulation sequence is applicable to a wide variety of enones except for those bearing substituents near the reacting centre." @default.
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- W2018337584 title "Cyclopentannulation of enones with organocuprate reagents containing an acetal or an orthoester function" @default.
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- W2018337584 doi "https://doi.org/10.1016/s0040-4020(01)01248-0" @default.
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