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- W2018339393 abstract "Pd0.77Ag0.23 alloy foil of thickness ∼100 μm was prepared by arc melting followed by cold rolling and annealing. The X-ray diffraction pattern confirmed the formation of solid solution phase and the TXRF analysis confirmed the composition as Pd0.77Ag0.23. Hydrogen/deuterium equilibrium pressure-composition-temperature (PCT) relationships for this alloy were experimentally generated over the temperature range of 374–419 K using Sieverts' type volumetric apparatus. Thermodynamic parameters like enthalpy and entropy of hydrogen/deuterium desorption reaction were evaluated from PCT data. Kinetics of hydrogen/deuterium absorption for this thin alloy foil was also investigated in the temperature range of 335–394 K using the same apparatus and activation energies of hydrogen/deuterium absorption reactions were evaluated. Both thermodynamic and kinetic data showed pronounced positive isotope effect in the temperature and pressure range of investigation." @default.
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- W2018339393 date "2015-01-01" @default.
- W2018339393 modified "2023-10-14" @default.
- W2018339393 title "Thermodynamics and kinetics of hydrogen/deuterium absorption–desorption in Pd 0.77 Ag 0.23 alloy" @default.
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- W2018339393 doi "https://doi.org/10.1016/j.ijhydene.2014.10.108" @default.
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