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- W2018340129 endingPage "8976" @default.
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- W2018340129 abstract "Two novel highly soluble triarylamine dendrimers TPAD1 and TPAD2 with N4,N6-dibutyl-1,3,5-triazine-4,6-diamine probe were synthesized via normal synthetic routes. Both dendrimers (TPAD1 and TPAD2) form H-bonded donor–acceptor–donor (D–A–D) supramolecular triads TPAD1-PBI-TPAD1 and TPAD2-PBI-TPAD2 with 3,4,9,10-perylene tetra carboxylic diimide derivative (PBI). The presence of multiple H-bonds in the solution state was elucidated by 1H NMR titrations and IR spectral studies. J-aggregations and electron/energy transfers provided by both dendrimers were verified by UV–Vis and photoluminescence (PL) titrations with PBI and the particle sizes of supramolecular triads were calculated by X-ray diffraction (XRD) analysis. Similarly, both dendrimers also showed sensitivities towards Cu2+ in comparison with 19 interfering metal ions, which were evidenced via UV–Vis and PL titraions in both single and dual metal systems. The maximum detection limit of Cu2+ ions was determined to be 20 ppm from PL titrations for both dendrimers, and the 1 : 2 stoichiometry of the complexes formed by both dendrimers (TPAD1-Cu2+ and TPAD2-Cu2+) were calculated by Job plots based on UV–Vis absorption titrations. More importantly, the binding mechanism of the 1,3,5-triazine-4,6-diamine probe of both dendrimers was well characterized by 1H and 13C NMR titrations ([D8]THF : D2O = 2 : 1 in vol.) and supported by the fluorescence reversibility by adding metal ions and PMDTA sequentially." @default.
- W2018340129 created "2016-06-24" @default.
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- W2018340129 date "2012-01-01" @default.
- W2018340129 modified "2023-10-16" @default.
- W2018340129 title "Synthesis of novel triarylamine-based dendrimers with N4,N6-dibutyl-1,3,5-triazine-4,6-diamine probe for electron/energy transfers in H-bonded donor–acceptor–donor triads and as efficient Cu2+ sensors" @default.
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- W2018340129 doi "https://doi.org/10.1039/c2jm00112h" @default.
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