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• W2018354413 abstract "Homochiral AB segments for (+)- and (–)-pillaromycinone were prepared in 11 steps from 2-acetylfuran. The synthesis featured an intramolecular Diels–Alder reaction of a 2,5-disubstituted furan and a hydroxyl-directed homogeneous hydrogenation of the tetrasubstituted alkene double bond of two enones. The CD segment was attached by a modified Staunton–Weinreb annulation to produce the desired homochiral tetracycle 21c related to (+)-pillaromycinone. An unusual acetonide migration enabled the synthesis of a tetracyclic model for premithramycinone." @default.
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• W2018354413 date "2011-12-01" @default.
• W2018354413 modified "2023-10-16" @default.
• W2018354413 title "A common synthetic route to homochiral tetracycles related to pillaromycinone and premithramycinone" @default.
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• W2018354413 doi "https://doi.org/10.1139/v11-119" @default.
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