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- W2018366115 abstract "Three new tris(aquo)-hexa-μ-glycinato-(μ3-O) complexes with the general formula [CrnFe3−n(μ3-O)(glycinate)6(H2O)3]X7·xH2O where n = 3, 2 or 1 have been prepared. The complexes have been characterised by analytical data, i.r. and electronic spectra and the [Fe2Cr-(μ3-O)(glycinate)6(H2O)3](ClO4)7·6H2O salt has been fully characterised by an X-ray single crystal study. The data for all three complexes are consistent with a planar triangular arrangement of metal atoms, a central μ3-O atom and six glycinate ligands which bridge across the metal centres using both oxygen atoms of the carboxylate groups i.e. retaining a zwitterion configuration. va M3O and vaMO′ modes have been assigned to the 550–650 and 360–460 cm−1 regions of the i.r. spectrum respectively and the electronic spectra of the three glycinates show absorptions which are typical of M3(μ3-O)planar bridged skeletons." @default.
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- W2018366115 title "Preparations and structures of some Tris(aquo)-hexa-μ-glycinato-μ3-oxo complexes, [Cr3Fe3−n(μ3-O)(glycine)6(H2O)3](NO3)7·xH2O" @default.
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- W2018366115 doi "https://doi.org/10.1016/s0020-1693(00)90742-4" @default.
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