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- W2018366693 abstract "The line-breadth parameters of a number of lines of the $X$-band magnetic resonance spectrum of ${mathrm{O}}_{2}$ have been measured and interpreted with the aid of a previously reported theory of the spectrum. The results are that the $M$-dependence of the line width is negligible, and there is only a slight decrease in width with increasing $K$. A typical width (half-width at half-intensity) at 300ifmmode^circelsetextdegreefi{}K is 2.2 (Mc/sec)/mm Hg. At pressures up to 8 mm Hg, the line centers have been found to shift less than 2 percent of the line width. The average temperature dependence of the normalized line breadth parameter ($frac{ensuremath{Delta}ensuremath{nu}}{P}$) is found to be ${T}^{ensuremath{-}0.75}$. This may be compared with the theoretical ${T}^{ensuremath{-}0.627}$ and the ${T}^{ensuremath{-}0.85}$ found by previous workers. We find ${mathrm{O}}_{2}$-${mathrm{N}}_{2}$ collisions to be no less effective than ${mathrm{O}}_{2}$-${mathrm{O}}_{2}$ collisions in producing broadening." @default.
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- W2018366693 date "1955-07-15" @default.
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- W2018366693 title "Line Breadths in the Microwave Magnetic Resonance Spectrum of Oxygen" @default.
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- W2018366693 doi "https://doi.org/10.1103/physrev.99.537" @default.
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