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- W2018367515 abstract "The densities and heat capacities of various alkali hydroxides were measured in water with a vibrating tube densimeter and a flow microcalorimeter in the temperature range 4 to 55 °C. The concentration ranges investigated were respectively: 0.04 to 3.8 mol kg −1 for LiOH, 0.02 to 10.9 mol kg −1 for NaOH, and 0.02 to 15.5 mol kg −1 for KOH. The partial molar volumes [Formula: see text] and heat capacities [Formula: see text]were calculated from the least-squares fit of the apparent molar quantities [Formula: see text] as a function of molalities. From the temperature dependence of these functions the apparent molar expansibilities [Formula: see text] and [Formula: see text] were derived. The ultrasonic velocities were also measured for the dilute solutions of NaOH at 25 °C, and can be used to calculate the standard partial molar compressibilities and isochoric heat capacities. The present data were compared with literature values. The general trends as a function of concentration are similar to those of other 1:1 electrolytes even though the deviations from the Debye–Hückel theory are larger." @default.
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- W2018367515 date "1984-05-01" @default.
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- W2018367515 title "Capacités calorifiques, volumes, expansibilités et compressibilités des solutions aqueuses concentrées de LiOH, NaOH et KOH" @default.
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- W2018367515 doi "https://doi.org/10.1139/v84-144" @default.
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