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- W2018376906 abstract "Direct β-glucosidation between 1,8-octanediol 5 and d-glucose 6 using the immobilized β-glucosidase (EC 3.2.1.21) from almonds with the synthetic prepolymer ENTP-4000 gave mono-β-glucoside 3 in 58% yield, which was converted into n-octyl β-d-glucopyranoside 2 by means of a chemoenzymatic method. The coupling of n-octyl β-d-glucopyranoside congener 15 and 2,3,4-tri-O-acetyl-α-l-arabinopyranosyl bromide 17, followed by deprotection afforded the synthetic rhodiooctanoside 1, which was identical with natural 1 with respect to the spectral data and specific rotation." @default.
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- W2018376906 date "2004-05-01" @default.
- W2018376906 modified "2023-10-14" @default.
- W2018376906 title "Chemoenzymatic synthesis of rhodiooctanoside isolated from Chinese medicines, rhodiolae radix" @default.
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- W2018376906 doi "https://doi.org/10.1016/j.tetasy.2004.03.046" @default.
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