FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2018387568> ?p ?o ?g. }

• W2018387568 endingPage "269" @default.
• W2018387568 startingPage "264" @default.
• W2018387568 abstract "The functionalization of “unprotected” Pt clusters with N-acetyl-cysteine (NAC) at different pH-values is presented that allows for binding NAC either via the thiol or the amide group to the particle. NMR-spectroscopy was used to study the chemical nature of NAC at weakly acidic and alkaline conditions. The formation of a cyclic isomer of NAC was found at high pH-values which occurs through an intramolecular reaction between the thiol and the amide group delivering a cyclic thioether. The absence of the bare thiol groups in aqueous alkaline solutions leads to binding of the cyclic isomer of NAC to the Pt clusters via its nitrogen atom. IR spectroscopy was applied, which confirmed that the cyclic isomer is, however, not stable upon drying, but undergoes ring-opening yielding the “normal” non-cyclic form. This distinctive property of NAC in combination with the use of “unprotected” clusters allows for binding the same ligand to clusters from the same batch, but with different binding modes, while the particle size is preserved. As a consequence, differences in the cluster properties can be related exclusively to the influence of the binding properties of the ligand. Finally, the catalytic hydrogenation of 2-butanone was used as a probe reaction and the resulting differences in the enantioselectivity can thus be related to this particular change in the binding mode." @default.
• W2018387568 created "2016-06-24" @default.
• W2018387568 creator A5003821229 @default.
• W2018387568 creator A5010875333 @default.
• W2018387568 creator A5017018085 @default.
• W2018387568 creator A5036044257 @default.
• W2018387568 creator A5048359310 @default.
• W2018387568 creator A5089799701 @default.
• W2018387568 date "2014-07-01" @default.
• W2018387568 modified "2023-09-24" @default.
• W2018387568 title "Same ligand – Different binding: A way to control the binding of N-acetyl-cysteine (NAC) to Pt clusters" @default.
• W2018387568 cites W1980122435 @default.
• W2018387568 cites W1994968669 @default.
• W2018387568 cites W2009731386 @default.
• W2018387568 cites W2011610178 @default.
• W2018387568 cites W2016807138 @default.
• W2018387568 cites W2019851175 @default.
• W2018387568 cites W2024383637 @default.
• W2018387568 cites W2027090069 @default.
• W2018387568 cites W2038417622 @default.
• W2018387568 cites W2043122802 @default.
• W2018387568 cites W2043376496 @default.
• W2018387568 cites W2064363432 @default.
• W2018387568 cites W2065636250 @default.
• W2018387568 cites W2070375674 @default.
• W2018387568 cites W2083876174 @default.
• W2018387568 cites W2083927163 @default.
• W2018387568 cites W2091265465 @default.
• W2018387568 cites W2097188869 @default.
• W2018387568 cites W2116770253 @default.
• W2018387568 cites W2119513716 @default.
• W2018387568 cites W2139683943 @default.
• W2018387568 cites W2141686621 @default.
• W2018387568 cites W2162598058 @default.
• W2018387568 cites W2317039198 @default.
• W2018387568 cites W2318062561 @default.
• W2018387568 cites W2321806205 @default.
• W2018387568 doi "https://doi.org/10.1016/j.jcis.2014.04.017" @default.
• W2018387568 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/24863792" @default.
• W2018387568 hasPublicationYear "2014" @default.
• W2018387568 type Work @default.
• W2018387568 sameAs 2018387568 @default.
• W2018387568 citedByCount "9" @default.
• W2018387568 countsByYear W20183875682015 @default.
• W2018387568 countsByYear W20183875682016 @default.
• W2018387568 countsByYear W20183875682018 @default.
• W2018387568 countsByYear W20183875682020 @default.
• W2018387568 crossrefType "journal-article" @default.
• W2018387568 hasAuthorship W2018387568A5003821229 @default.
• W2018387568 hasAuthorship W2018387568A5010875333 @default.
• W2018387568 hasAuthorship W2018387568A5017018085 @default.
• W2018387568 hasAuthorship W2018387568A5036044257 @default.
• W2018387568 hasAuthorship W2018387568A5048359310 @default.
• W2018387568 hasAuthorship W2018387568A5089799701 @default.
• W2018387568 hasConcept C116569031 @default.
• W2018387568 hasConcept C155647269 @default.
• W2018387568 hasConcept C170493617 @default.
• W2018387568 hasConcept C178790620 @default.
• W2018387568 hasConcept C181199279 @default.
• W2018387568 hasConcept C184651966 @default.
• W2018387568 hasConcept C185592680 @default.
• W2018387568 hasConcept C2778439535 @default.
• W2018387568 hasConcept C2779201268 @default.
• W2018387568 hasConcept C2779444094 @default.
• W2018387568 hasConcept C2781324293 @default.
• W2018387568 hasConcept C55493867 @default.
• W2018387568 hasConcept C66974803 @default.
• W2018387568 hasConcept C71240020 @default.
• W2018387568 hasConcept C75079739 @default.
• W2018387568 hasConceptScore W2018387568C116569031 @default.
• W2018387568 hasConceptScore W2018387568C155647269 @default.
• W2018387568 hasConceptScore W2018387568C170493617 @default.
• W2018387568 hasConceptScore W2018387568C178790620 @default.
• W2018387568 hasConceptScore W2018387568C181199279 @default.
• W2018387568 hasConceptScore W2018387568C184651966 @default.
• W2018387568 hasConceptScore W2018387568C185592680 @default.
• W2018387568 hasConceptScore W2018387568C2778439535 @default.
• W2018387568 hasConceptScore W2018387568C2779201268 @default.
• W2018387568 hasConceptScore W2018387568C2779444094 @default.
• W2018387568 hasConceptScore W2018387568C2781324293 @default.
• W2018387568 hasConceptScore W2018387568C55493867 @default.
• W2018387568 hasConceptScore W2018387568C66974803 @default.
• W2018387568 hasConceptScore W2018387568C71240020 @default.
• W2018387568 hasConceptScore W2018387568C75079739 @default.
• W2018387568 hasLocation W20183875681 @default.
• W2018387568 hasLocation W20183875682 @default.
• W2018387568 hasOpenAccess W2018387568 @default.
• W2018387568 hasPrimaryLocation W20183875681 @default.
• W2018387568 hasRelatedWork W2052634481 @default.
• W2018387568 hasRelatedWork W2068831529 @default.
• W2018387568 hasRelatedWork W2091942882 @default.
• W2018387568 hasRelatedWork W2157295921 @default.
• W2018387568 hasRelatedWork W2163680631 @default.
• W2018387568 hasRelatedWork W2952858766 @default.
• W2018387568 hasRelatedWork W3118402337 @default.
• W2018387568 hasRelatedWork W3204078051 @default.
• W2018387568 hasRelatedWork W4293226730 @default.
• W2018387568 hasRelatedWork W4365479004 @default.

• next