Matches in SemOpenAlex for { <https://semopenalex.org/work/W2018392330> ?p ?o ?g. }
- W2018392330 endingPage "217" @default.
- W2018392330 startingPage "209" @default.
- W2018392330 abstract "Dichlorocarbene (CCl2), generated by laser flash photolysis of dichlorodiazirine, formed π- and O-ylidic complexes with aromatic ethers such as anisole, 1,3-dimethoxybenzene, 1,3,5-trimethoxybenzene, dibenzofuran, and dibenzo-18-crown-6 and with the aromatic ester phenyl acetate. These complexes were visualized by UV−vis spectroscopy, and they retarded the addition of CCl2 to tetramethylethylene by factors of 18−152. Computational studies based on density functional theory provided structures and energetics for the transient species and rationalized their absorption spectra. Complexes were not observed between CCl2 and simple, nonaromatic ethers such as THF, dioxane, or 18-crown-6, nor did these ethers much affect the addition rate of CCl2 to tetramethylethylene. Computations also suggested that π-complexes of CCl2 and, e.g., mesitylene and durene, were energetically reasonable transients. Although these species were not detected spectroscopically, the aromatic compounds did slow the addition of CCl2 to tetramethylethylene by factors of 15 and 31, respectively." @default.
- W2018392330 created "2016-06-24" @default.
- W2018392330 creator A5033172242 @default.
- W2018392330 creator A5043487387 @default.
- W2018392330 creator A5046775614 @default.
- W2018392330 creator A5073216396 @default.
- W2018392330 creator A5073345526 @default.
- W2018392330 date "2009-10-30" @default.
- W2018392330 modified "2023-09-26" @default.
- W2018392330 title "Solvation of Dichlorocarbene: Complexation with Aryl Ethers" @default.
- W2018392330 cites W1479688961 @default.
- W2018392330 cites W1967302110 @default.
- W2018392330 cites W1968210086 @default.
- W2018392330 cites W1968599600 @default.
- W2018392330 cites W1971275758 @default.
- W2018392330 cites W1973993486 @default.
- W2018392330 cites W1975708211 @default.
- W2018392330 cites W1976268386 @default.
- W2018392330 cites W1981368803 @default.
- W2018392330 cites W1987546107 @default.
- W2018392330 cites W1990637909 @default.
- W2018392330 cites W1996672707 @default.
- W2018392330 cites W1997492269 @default.
- W2018392330 cites W2018542890 @default.
- W2018392330 cites W2020770689 @default.
- W2018392330 cites W2023271753 @default.
- W2018392330 cites W2030590645 @default.
- W2018392330 cites W2033216608 @default.
- W2018392330 cites W2033562527 @default.
- W2018392330 cites W2038767330 @default.
- W2018392330 cites W2058848030 @default.
- W2018392330 cites W2059248293 @default.
- W2018392330 cites W2060851444 @default.
- W2018392330 cites W2061870929 @default.
- W2018392330 cites W2069197437 @default.
- W2018392330 cites W2071643645 @default.
- W2018392330 cites W2074271730 @default.
- W2018392330 cites W2084633804 @default.
- W2018392330 cites W2120436453 @default.
- W2018392330 cites W2153890042 @default.
- W2018392330 cites W2164318957 @default.
- W2018392330 cites W2952022811 @default.
- W2018392330 doi "https://doi.org/10.1021/jp9075542" @default.
- W2018392330 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/19877654" @default.
- W2018392330 hasPublicationYear "2009" @default.
- W2018392330 type Work @default.
- W2018392330 sameAs 2018392330 @default.
- W2018392330 citedByCount "20" @default.
- W2018392330 countsByYear W20183923302012 @default.
- W2018392330 countsByYear W20183923302013 @default.
- W2018392330 countsByYear W20183923302014 @default.
- W2018392330 countsByYear W20183923302015 @default.
- W2018392330 countsByYear W20183923302016 @default.
- W2018392330 countsByYear W20183923302017 @default.
- W2018392330 crossrefType "journal-article" @default.
- W2018392330 hasAuthorship W2018392330A5033172242 @default.
- W2018392330 hasAuthorship W2018392330A5043487387 @default.
- W2018392330 hasAuthorship W2018392330A5046775614 @default.
- W2018392330 hasAuthorship W2018392330A5073216396 @default.
- W2018392330 hasAuthorship W2018392330A5073345526 @default.
- W2018392330 hasConcept C121332964 @default.
- W2018392330 hasConcept C13472781 @default.
- W2018392330 hasConcept C148898269 @default.
- W2018392330 hasConcept C155647269 @default.
- W2018392330 hasConcept C161790260 @default.
- W2018392330 hasConcept C178790620 @default.
- W2018392330 hasConcept C185592680 @default.
- W2018392330 hasConcept C2776404417 @default.
- W2018392330 hasConcept C2776513212 @default.
- W2018392330 hasConcept C2777352791 @default.
- W2018392330 hasConcept C2777458374 @default.
- W2018392330 hasConcept C2777691172 @default.
- W2018392330 hasConcept C2780263894 @default.
- W2018392330 hasConcept C2780400710 @default.
- W2018392330 hasConcept C2781039906 @default.
- W2018392330 hasConcept C2781076698 @default.
- W2018392330 hasConcept C62520636 @default.
- W2018392330 hasConcept C75473681 @default.
- W2018392330 hasConcept C93391505 @default.
- W2018392330 hasConceptScore W2018392330C121332964 @default.
- W2018392330 hasConceptScore W2018392330C13472781 @default.
- W2018392330 hasConceptScore W2018392330C148898269 @default.
- W2018392330 hasConceptScore W2018392330C155647269 @default.
- W2018392330 hasConceptScore W2018392330C161790260 @default.
- W2018392330 hasConceptScore W2018392330C178790620 @default.
- W2018392330 hasConceptScore W2018392330C185592680 @default.
- W2018392330 hasConceptScore W2018392330C2776404417 @default.
- W2018392330 hasConceptScore W2018392330C2776513212 @default.
- W2018392330 hasConceptScore W2018392330C2777352791 @default.
- W2018392330 hasConceptScore W2018392330C2777458374 @default.
- W2018392330 hasConceptScore W2018392330C2777691172 @default.
- W2018392330 hasConceptScore W2018392330C2780263894 @default.
- W2018392330 hasConceptScore W2018392330C2780400710 @default.
- W2018392330 hasConceptScore W2018392330C2781039906 @default.
- W2018392330 hasConceptScore W2018392330C2781076698 @default.
- W2018392330 hasConceptScore W2018392330C62520636 @default.
- W2018392330 hasConceptScore W2018392330C75473681 @default.
- W2018392330 hasConceptScore W2018392330C93391505 @default.