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- W2018405909 abstract "The reactions of N-alkylsulfamoyl chloride with enamines in the presence of triethylamine showed the presence of N-alkylsulfonyl imide (RN=SO2) as a reaction intermediate to give either acyclic (sulfonamides) or cyclic products (1,2-thiazetidine 1,1-dioxides), depending upon the enamines used. The enamines leading to the acyclic products possess either a methylene group on the α-carbon or a hydrogen on the β-carbon of the enamine; the enamine leading to the cyclic product has no such available hydrogen atom. It is thought that the products are formed via a zwitter ionic intermediate provided by the electrophilic attack of the sulfonyl imide sulfur atom on the β-carbon atom of the enamine." @default.
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- W2018405909 date "1979-04-01" @default.
- W2018405909 modified "2023-09-27" @default.
- W2018405909 title "On the Behavior of Sulfonyl Imide as a Reactive Intermediate. The Reaction with Enamines" @default.
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