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• W2018432983 abstract "Magnetic susceptibility and EPR studies show that trinuclear Cu(II)-pyrazolato complexes with a Cu(3)(mu3-X)2 core (X = Cl, Br) are ferromagnetically coupled: J(Cu-Cu) = +28.6 cm(-1) (X = Cl), +3.1 cm(-1) (X = Br). The orderly transition from an antiferromagnetic to a ferromagnetic exchange among the Cu centers of Cu(3)(mu3-X) complexes, X = O, OH, Cl, Br, follows the change of the Cu-X-Cu angle from 120 degrees to approximately 80 degrees. The crystal structures of [Bu4N]2[Cu3(mu3-Br)2(mu-pz*)3Br3] (pz* = pz (1a) or 4-O2N-pz (1b), pz = pyrazolato anion, C(3)H(3)N(2)(1-)) are presented." @default.
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• W2018432983 date "2003-08-22" @default.
• W2018432983 modified "2023-10-13" @default.
• W2018432983 title "Triangular, Ferromagnetically-Coupled Cu^II₃−Pyrazolato Complexes as Possible Models of Particulate Methane Monooxygenase (pMMO)" @default.
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• W2018432983 doi "https://doi.org/10.1021/ic0344416" @default.
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