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• W2018441502 abstract "Abstract The NMR spectra of aqueous solutions of malonic, methyl malonic, and isopropyl malonic acids have been examined over a wide pH range and variations in chemical shifts, line widths, and coupling parameters have been observed. Significant differences in the behavior of the proton—proton coupling (H α H β ) in methyl and isopropyl acids have been interpreted in terms of steric interactions which affect the rotamer populations over which the coupling is averaged. The occurrence of a minimum in this coupling for the isopropyl acid is attributed to an internally H-bonded structure which is most stable in the singly ionized acid." @default.
• W2018441502 created "2016-06-24" @default.
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• W2018441502 date "1968-01-01" @default.
• W2018441502 modified "2023-09-27" @default.
• W2018441502 title "An investigation of intramolecular hydrogen bonding in some malonic acids using NMR techniques" @default.
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• W2018441502 doi "https://doi.org/10.1016/0584-8539(68)80010-8" @default.
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