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- W2018454145 abstract "Abstract He(I) photoelectron spectroscopic (PE) measurements and ab initio calculations were performed on tetramethyldistibane. The spectroscopic measurements gave clear evidence for the existence of gauche and anti conformers in the gas phase. The composition of the rotameric mixture is 12% gauche and 88% anti conformers, estimated on the basis of the corresponding PE band areas. The Hartree-Fock calculations were performed using both effective core potential and all-electron 3–21 Gaussian basis sets. Full geometry optimizations were applied, resulting in theoretical evidence for the existence of the two rotamers. The calculated ionization energies seem to necessitate further studies on the assignment of the PE bands related to the antimony lone pairs." @default.
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- W2018454145 date "1996-05-01" @default.
- W2018454145 modified "2023-10-15" @default.
- W2018454145 title "Rotational isomerism in tetramethyldistibane studied by UV photoelectron spectroscopy" @default.
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- W2018454145 doi "https://doi.org/10.1016/0022-328x(95)06106-7" @default.
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