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• W2018478814 startingPage "392" @default.
• W2018478814 abstract "The mechanism of silicon−fluorine and silicon−carbon bond cleavage in organofluorosilanes and -silicates is analyzed with the aid of molecular orbital calculations. The optimized geometries of reactants and intermediates are calculated, and these calculations support the view that cleavage of Si−F bonds occurs by way of fluorine-bridged Si--F--Si intermediates. Cleavage of a Si−C bond in PhSiF3 takes place in the presence of fluoride ion and oxidizing agents, and the calculations are in agreement with the formation of PhSiF4- and PhSiF52-, followed by oxidation to a radical anion PhSiF5•-. The latter species, however, is predicted to decompose rapidly to give anionic SiF5-, and phenyl radicals. These calculations and the proposed mechanisms of bond cleavage are in agreement with experimental data, where available." @default.
• W2018478814 created "2016-06-24" @default.
• W2018478814 creator A5004963667 @default.
• W2018478814 creator A5043805828 @default.
• W2018478814 date "1997-01-01" @default.
• W2018478814 modified "2023-10-18" @default.
• W2018478814 title "Silicon−Fluorine and Silicon−Carbon Bond Cleavage in Organofluorosilicates: A Molecular Orbital Study" @default.
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• W2018478814 doi "https://doi.org/10.1021/ic940888q" @default.
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