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- W2018484561 abstract "The phase stability in part of the P 2 O 5 ‐bearing pseudoquaternary system CaO–SiO 2 –Al 2 O 3 –Fe 2 O 3 has been studied by electron probe microanalysis, optical microscopy, and powder X‐ray diffractometry. At 1973–1653 K, the α‐Ca 2 SiO 4 solid solution [α‐C 2 S(ss)] and melt coexisted in equilibrium, both chemical variations of which were determined as a function of temperature. The three phases of melt, calcium aluminoferrite solid solution (ferrite), and C 2 S(ss) coexisted at 1673–1598 K. On the basis of the chemical compositions of these phases, a melt‐differentiation mechanism has been, for the first time, suggested to account for the crystallization behavior of Ca 3 Al 2 O 6 solid solution [C 3 A(ss)]. When the α‐C 2 S(ss) and melt were cooled from high temperatures, the melt would be induced to differentiate by the crystallization of ferrite. Because the local equilibrium would be continually attained between the rims of the precipitating ferrite and coexisting melt during further cooling, the melt would progressively become enriched in Al 2 O 3 with respect to Fe 2 O 3 . The resulting ferrite crystals would show the zonal structure, with the Al/(Al+Fe) value steadily increasing up to 0.7 from the cores toward the rims. The C 3 A(ss) would eventually crystallize out of the differentiated melt between the zoned ferrite crystals in contact with their rims." @default.
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- W2018484561 date "2005-03-17" @default.
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- W2018484561 title "Melt Differentiation Induced by Zonal Structure Formation of Calcium Aluminoferrite in a CaO-SiO2-Al2O3-Fe2O3 Pseudoquaternary System" @default.
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- W2018484561 doi "https://doi.org/10.1111/j.1551-2916.2005.00182.x" @default.
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