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- W2018499293 abstract "Abstract The aldol reaction of a chiral N ‐(acyl)oxazolidin‐2‐one with 2‐methyleneoctanal or ( E )‐2‐methyloct‐2‐enal affords chiral aldol products whose alkene functionalities were hydrogenated using Brown's or Wilkinson's catalyst to afford syn ‐ or anti ‐selective products with excellent levels of diastereocontrol. Subsequent retro ‐aldol cleavage of these syn ‐ or anti ‐adducts resulted in the formation of either ( R )‐ or ( S )‐enantiomer of α‐methyloctanal with no racemisation occurring, which could be derivatised in‐situ to afford chiral dithiane, alcohol or α,β‐unsaturated ester products in enantiopure form.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)" @default.
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- W2018499293 date "2007-10-30" @default.
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- W2018499293 title "A Temporary Stereocentre Approach for the Stereodivergent Synthesis of Either Enantiomer of α-Methyloctanal" @default.
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- W2018499293 doi "https://doi.org/10.1002/ejoc.200700782" @default.
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