Matches in SemOpenAlex for { <https://semopenalex.org/work/W2018523256> ?p ?o ?g. }
- W2018523256 endingPage "8143" @default.
- W2018523256 startingPage "8137" @default.
- W2018523256 abstract "Poly(vinyl alcohol), PVOH, films have been studied as a function of water content. The states of water present in the polymer (bound or free) have been characterized and are a function of water content. The effects of water content (and hence state) on the free volume, chain mobility, and glass transition (Tg) behavior have been studied by positron annihilation lifetime spectroscopy, 13C solid state nuclear magnetic resonance, and dynamic mechanical analysis. The addition of approximately 30 wt % water results in a marked increase in free volume cavity size and polymer chain mobility and a corresponding decrease in Tg. The water is in a molecular, nonfreezable state for water additions up to approximately 30 wt %, hence it is postulated that nonfreezing water is responsible for the majority of the plasticization in this system. The plasticization is attributed to the increasing free volume and lubrication provided as the water swells the polymer and disrupts polymer−polymer hydrogen bonding. A limited equivalence between the action of water on the polymer and the action of temperature (thermal energy) is proposed." @default.
- W2018523256 created "2016-06-24" @default.
- W2018523256 creator A5016555639 @default.
- W2018523256 creator A5022623156 @default.
- W2018523256 creator A5025978464 @default.
- W2018523256 creator A5062458918 @default.
- W2018523256 creator A5089317111 @default.
- W2018523256 date "1996-01-01" @default.
- W2018523256 modified "2023-10-01" @default.
- W2018523256 title "Free Volume and the Mechanism of Plasticization in Water-Swollen Poly(vinyl alcohol)" @default.
- W2018523256 cites W1918373717 @default.
- W2018523256 cites W1966976584 @default.
- W2018523256 cites W1977741766 @default.
- W2018523256 cites W1977772628 @default.
- W2018523256 cites W1979527796 @default.
- W2018523256 cites W1985045072 @default.
- W2018523256 cites W1988955292 @default.
- W2018523256 cites W1992992457 @default.
- W2018523256 cites W2000375978 @default.
- W2018523256 cites W2005312792 @default.
- W2018523256 cites W2008517705 @default.
- W2018523256 cites W2010167353 @default.
- W2018523256 cites W2011043063 @default.
- W2018523256 cites W2015228479 @default.
- W2018523256 cites W2016226232 @default.
- W2018523256 cites W2027663011 @default.
- W2018523256 cites W2031370417 @default.
- W2018523256 cites W2033958088 @default.
- W2018523256 cites W2036959921 @default.
- W2018523256 cites W2038781014 @default.
- W2018523256 cites W2040544975 @default.
- W2018523256 cites W2047948690 @default.
- W2018523256 cites W2052884462 @default.
- W2018523256 cites W2063429697 @default.
- W2018523256 cites W2065224526 @default.
- W2018523256 cites W2066917557 @default.
- W2018523256 cites W2067115421 @default.
- W2018523256 cites W2070556457 @default.
- W2018523256 cites W2072445875 @default.
- W2018523256 cites W2082120436 @default.
- W2018523256 cites W2084730621 @default.
- W2018523256 cites W2087691168 @default.
- W2018523256 cites W2123536861 @default.
- W2018523256 cites W2159000130 @default.
- W2018523256 cites W4240990580 @default.
- W2018523256 cites W4246699049 @default.
- W2018523256 cites W4249011824 @default.
- W2018523256 doi "https://doi.org/10.1021/ma951073j" @default.
- W2018523256 hasPublicationYear "1996" @default.
- W2018523256 type Work @default.
- W2018523256 sameAs 2018523256 @default.
- W2018523256 citedByCount "277" @default.
- W2018523256 countsByYear W20185232562012 @default.
- W2018523256 countsByYear W20185232562013 @default.
- W2018523256 countsByYear W20185232562014 @default.
- W2018523256 countsByYear W20185232562015 @default.
- W2018523256 countsByYear W20185232562016 @default.
- W2018523256 countsByYear W20185232562017 @default.
- W2018523256 countsByYear W20185232562018 @default.
- W2018523256 countsByYear W20185232562019 @default.
- W2018523256 countsByYear W20185232562020 @default.
- W2018523256 countsByYear W20185232562021 @default.
- W2018523256 countsByYear W20185232562022 @default.
- W2018523256 countsByYear W20185232562023 @default.
- W2018523256 crossrefType "journal-article" @default.
- W2018523256 hasAuthorship W2018523256A5016555639 @default.
- W2018523256 hasAuthorship W2018523256A5022623156 @default.
- W2018523256 hasAuthorship W2018523256A5025978464 @default.
- W2018523256 hasAuthorship W2018523256A5062458918 @default.
- W2018523256 hasAuthorship W2018523256A5089317111 @default.
- W2018523256 hasConcept C121332964 @default.
- W2018523256 hasConcept C122865956 @default.
- W2018523256 hasConcept C127413603 @default.
- W2018523256 hasConcept C15920480 @default.
- W2018523256 hasConcept C178790620 @default.
- W2018523256 hasConcept C185592680 @default.
- W2018523256 hasConcept C187320778 @default.
- W2018523256 hasConcept C188027245 @default.
- W2018523256 hasConcept C192562407 @default.
- W2018523256 hasConcept C20556612 @default.
- W2018523256 hasConcept C24939127 @default.
- W2018523256 hasConcept C2776171763 @default.
- W2018523256 hasConcept C2780666587 @default.
- W2018523256 hasConcept C2992078993 @default.
- W2018523256 hasConcept C32909587 @default.
- W2018523256 hasConcept C42360764 @default.
- W2018523256 hasConcept C521977710 @default.
- W2018523256 hasConcept C58968531 @default.
- W2018523256 hasConcept C73673656 @default.
- W2018523256 hasConcept C87717796 @default.
- W2018523256 hasConcept C97355855 @default.
- W2018523256 hasConceptScore W2018523256C121332964 @default.
- W2018523256 hasConceptScore W2018523256C122865956 @default.
- W2018523256 hasConceptScore W2018523256C127413603 @default.
- W2018523256 hasConceptScore W2018523256C15920480 @default.
- W2018523256 hasConceptScore W2018523256C178790620 @default.
- W2018523256 hasConceptScore W2018523256C185592680 @default.
- W2018523256 hasConceptScore W2018523256C187320778 @default.