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- W2018538354 abstract "In order to get some idea for the magnitude of the anharmonicity constants for the stretching SO4 vibrations in K2SO4, the FT IR spectra of K2CrO4 containing small amount of K2SO4 were recorded at LNT, in the 2350-500 cm−1 region. All stretching fundamentals were preciselly measured, as well as nine of ten possible second-order transitions. Combination bands between stretching and bending vibrations could not be identified in the spectra of the mixed crystals. The analogous bands in pure K2SO4 are probably of very low intensity, thus indicating that the corresponding anharmonicity constants could be neglected. Using suitable equations [1], the values for the harmonic (zero-order) frequencies of the antisymmetric stretching fundamentals and anharmonicity constants were calculated." @default.
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- W2018538354 date "1990-03-01" @default.
- W2018538354 modified "2023-09-27" @default.
- W2018538354 title "Harmonic frequencies and anharmonicity constants for the antisymmetric SO4 stretching vibrations of isomorphously isolated SO4 ions in K2CrO4" @default.
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- W2018538354 doi "https://doi.org/10.1016/0022-2860(90)80051-k" @default.
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