Matches in SemOpenAlex for { <https://semopenalex.org/work/W2018547135> ?p ?o ?g. }
- W2018547135 endingPage "12" @default.
- W2018547135 startingPage "5" @default.
- W2018547135 abstract "The mechanisms of adsorption and association for sodium carboxymethylcellulose (NaCMC) in calcium carbonate suspensions have been determined from isothermal calorimetry and adsorption measurements. The equilibrium adsorption isotherms were determined by two different methods of separation; a depletion method and a serum exchange method. The enthalpy of dilution for NaCMC was determined on supernatants obtained from the calcium carbonate suspensions in order to investigate the interaction between NaCMC and dissolved species from the mineral. For comparison, NaCMC was injected into CaCl(2) solutions in order to determine the role of calcium ions in the adsorption process. The initial part of the adsorption isotherm showed a quasi-infinite slope indicating a high affinity for the NaCMC to the calcium carbonate surface, which was significantly reduced when anionic sodium polyacrylate was preadsorbed onto the calcium carbonate implying competitive adsorption. An endothermic enthalpy change was observed between the NaCMC and the calcium carbonate surface, suggesting attachment of the carboxylic acid groups onto the hydrated calcium sites. A similar endothermic enthalpy was observed when NaCMC was injected into CaCl(2) solutions or supernatants obtained from the calcium carbonate suspensions, indicating a complexation of carboxylic acid groups and hydrated calcium ions. It was concluded that the mechanisms of interaction of NaCMC in calcium carbonate suspensions are primarily an association between NaCMC and Lewis acid sites on the calcium carbonate surface and the formation of NaCMC-Ca(2+) complexes in the bulk solution, both of which will be affected by the amount of anionic sodium polyacrylate present." @default.
- W2018547135 created "2016-06-24" @default.
- W2018547135 creator A5022099184 @default.
- W2018547135 creator A5044591982 @default.
- W2018547135 creator A5054264937 @default.
- W2018547135 creator A5055108767 @default.
- W2018547135 date "2002-04-01" @default.
- W2018547135 modified "2023-09-25" @default.
- W2018547135 title "Aspects on the Interaction between Sodium Carboxymethylcellulose and Calcium Carbonate and the Relationship to Specific Site Adsorption" @default.
- W2018547135 cites W1524124163 @default.
- W2018547135 cites W1964428295 @default.
- W2018547135 cites W1968834637 @default.
- W2018547135 cites W1976301588 @default.
- W2018547135 cites W1982569911 @default.
- W2018547135 cites W1984745291 @default.
- W2018547135 cites W1988992725 @default.
- W2018547135 cites W1990475855 @default.
- W2018547135 cites W1997068351 @default.
- W2018547135 cites W2000698443 @default.
- W2018547135 cites W2006001192 @default.
- W2018547135 cites W2007037910 @default.
- W2018547135 cites W2015873836 @default.
- W2018547135 cites W2019480914 @default.
- W2018547135 cites W2020661061 @default.
- W2018547135 cites W2020859648 @default.
- W2018547135 cites W2021687526 @default.
- W2018547135 cites W2029154947 @default.
- W2018547135 cites W2045731096 @default.
- W2018547135 cites W2058573155 @default.
- W2018547135 cites W2060605459 @default.
- W2018547135 cites W2063254793 @default.
- W2018547135 cites W2065193344 @default.
- W2018547135 cites W2068224218 @default.
- W2018547135 cites W2075966524 @default.
- W2018547135 cites W2076032530 @default.
- W2018547135 cites W2077126431 @default.
- W2018547135 cites W2086785003 @default.
- W2018547135 doi "https://doi.org/10.1006/jcis.2001.8195" @default.
- W2018547135 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/16290496" @default.
- W2018547135 hasPublicationYear "2002" @default.
- W2018547135 type Work @default.
- W2018547135 sameAs 2018547135 @default.
- W2018547135 citedByCount "49" @default.
- W2018547135 countsByYear W20185471352012 @default.
- W2018547135 countsByYear W20185471352014 @default.
- W2018547135 countsByYear W20185471352015 @default.
- W2018547135 countsByYear W20185471352016 @default.
- W2018547135 countsByYear W20185471352017 @default.
- W2018547135 countsByYear W20185471352018 @default.
- W2018547135 countsByYear W20185471352019 @default.
- W2018547135 countsByYear W20185471352020 @default.
- W2018547135 countsByYear W20185471352021 @default.
- W2018547135 countsByYear W20185471352022 @default.
- W2018547135 crossrefType "journal-article" @default.
- W2018547135 hasAuthorship W2018547135A5022099184 @default.
- W2018547135 hasAuthorship W2018547135A5044591982 @default.
- W2018547135 hasAuthorship W2018547135A5054264937 @default.
- W2018547135 hasAuthorship W2018547135A5055108767 @default.
- W2018547135 hasConcept C121332964 @default.
- W2018547135 hasConcept C150394285 @default.
- W2018547135 hasConcept C178790620 @default.
- W2018547135 hasConcept C179104552 @default.
- W2018547135 hasConcept C185592680 @default.
- W2018547135 hasConcept C206139338 @default.
- W2018547135 hasConcept C20976626 @default.
- W2018547135 hasConcept C2778039128 @default.
- W2018547135 hasConcept C2779173332 @default.
- W2018547135 hasConcept C3288061 @default.
- W2018547135 hasConcept C519063684 @default.
- W2018547135 hasConcept C97355855 @default.
- W2018547135 hasConceptScore W2018547135C121332964 @default.
- W2018547135 hasConceptScore W2018547135C150394285 @default.
- W2018547135 hasConceptScore W2018547135C178790620 @default.
- W2018547135 hasConceptScore W2018547135C179104552 @default.
- W2018547135 hasConceptScore W2018547135C185592680 @default.
- W2018547135 hasConceptScore W2018547135C206139338 @default.
- W2018547135 hasConceptScore W2018547135C20976626 @default.
- W2018547135 hasConceptScore W2018547135C2778039128 @default.
- W2018547135 hasConceptScore W2018547135C2779173332 @default.
- W2018547135 hasConceptScore W2018547135C3288061 @default.
- W2018547135 hasConceptScore W2018547135C519063684 @default.
- W2018547135 hasConceptScore W2018547135C97355855 @default.
- W2018547135 hasIssue "1" @default.
- W2018547135 hasLocation W20185471351 @default.
- W2018547135 hasLocation W20185471352 @default.
- W2018547135 hasOpenAccess W2018547135 @default.
- W2018547135 hasPrimaryLocation W20185471351 @default.
- W2018547135 hasRelatedWork W2052334463 @default.
- W2018547135 hasRelatedWork W2072027891 @default.
- W2018547135 hasRelatedWork W2348804876 @default.
- W2018547135 hasRelatedWork W2357334156 @default.
- W2018547135 hasRelatedWork W2361631209 @default.
- W2018547135 hasRelatedWork W2364796674 @default.
- W2018547135 hasRelatedWork W2371014114 @default.
- W2018547135 hasRelatedWork W2391365298 @default.
- W2018547135 hasRelatedWork W2752238565 @default.
- W2018547135 hasRelatedWork W2774575834 @default.
- W2018547135 hasVolume "248" @default.