Matches in SemOpenAlex for { <https://semopenalex.org/work/W2018553833> ?p ?o ?g. }
- W2018553833 endingPage "91" @default.
- W2018553833 startingPage "85" @default.
- W2018553833 abstract "Ortho-bis(fluorosilyl)benzenes, precursors for bis-siliconates, o-C6H4(SiPhF2)2 (1), o-C6H4(SiF3)(SiPh2F) (2) and o-C6H4(SiF3)(SiPh2F) (3), possess anion binding properties as bidentate Lewis acidic hosts in organic solvents, Compound 1 quantitatively binds a fluoride ion from KF suspended in aceton or tetrahydrofruan without support of 18-crown-6 to form the corresponding soluble bis-siliconate [o-C6H4(SiPhF2)2F]K (4). The binding constants of a series of fluorosilanes for a fluoride ion are measured by 1H and 19F NMR spectroscopies. The affinity of fluorosilanes towards a fluoride ion increases in the order PhMeSiF2 (7) 1.1 × 109 M−1 at 193 K. These bidentate Lewis acids 1–3 are among the strongest organic hosts for a fluoride ion in organic solvents ever reported." @default.
- W2018553833 created "2016-06-24" @default.
- W2018553833 creator A5021407407 @default.
- W2018553833 creator A5033239179 @default.
- W2018553833 creator A5034939239 @default.
- W2018553833 date "1996-01-01" @default.
- W2018553833 modified "2023-09-26" @default.
- W2018553833 title "Anion complexation by bidentate Lewis acidic hosts, ortho-bis(fluorosilyl) benzenes" @default.
- W2018553833 cites W1964023477 @default.
- W2018553833 cites W1966878059 @default.
- W2018553833 cites W1970749683 @default.
- W2018553833 cites W1971415038 @default.
- W2018553833 cites W1980439105 @default.
- W2018553833 cites W1982306030 @default.
- W2018553833 cites W1991139785 @default.
- W2018553833 cites W1996924326 @default.
- W2018553833 cites W1998170765 @default.
- W2018553833 cites W1998283630 @default.
- W2018553833 cites W1998772016 @default.
- W2018553833 cites W2003071113 @default.
- W2018553833 cites W2005340511 @default.
- W2018553833 cites W2005833840 @default.
- W2018553833 cites W2005914546 @default.
- W2018553833 cites W2008657303 @default.
- W2018553833 cites W2017675618 @default.
- W2018553833 cites W2017952495 @default.
- W2018553833 cites W2026372755 @default.
- W2018553833 cites W2026770983 @default.
- W2018553833 cites W2028444801 @default.
- W2018553833 cites W2029957897 @default.
- W2018553833 cites W2032439659 @default.
- W2018553833 cites W2037849444 @default.
- W2018553833 cites W2043400313 @default.
- W2018553833 cites W2047879486 @default.
- W2018553833 cites W2049419255 @default.
- W2018553833 cites W2055040078 @default.
- W2018553833 cites W2058387957 @default.
- W2018553833 cites W2059853344 @default.
- W2018553833 cites W2073320702 @default.
- W2018553833 cites W2073642300 @default.
- W2018553833 cites W2080623022 @default.
- W2018553833 cites W2084348846 @default.
- W2018553833 cites W2086924033 @default.
- W2018553833 cites W2091103713 @default.
- W2018553833 cites W2101479143 @default.
- W2018553833 cites W2321972685 @default.
- W2018553833 cites W2328522705 @default.
- W2018553833 cites W2952176378 @default.
- W2018553833 cites W2953355221 @default.
- W2018553833 doi "https://doi.org/10.1016/0022-328x(95)05636-4" @default.
- W2018553833 hasPublicationYear "1996" @default.
- W2018553833 type Work @default.
- W2018553833 sameAs 2018553833 @default.
- W2018553833 citedByCount "66" @default.
- W2018553833 countsByYear W20185538332013 @default.
- W2018553833 countsByYear W20185538332014 @default.
- W2018553833 countsByYear W20185538332015 @default.
- W2018553833 countsByYear W20185538332016 @default.
- W2018553833 countsByYear W20185538332017 @default.
- W2018553833 countsByYear W20185538332019 @default.
- W2018553833 countsByYear W20185538332020 @default.
- W2018553833 countsByYear W20185538332022 @default.
- W2018553833 countsByYear W20185538332023 @default.
- W2018553833 crossrefType "journal-article" @default.
- W2018553833 hasAuthorship W2018553833A5021407407 @default.
- W2018553833 hasAuthorship W2018553833A5033239179 @default.
- W2018553833 hasAuthorship W2018553833A5034939239 @default.
- W2018553833 hasConcept C115624301 @default.
- W2018553833 hasConcept C145148216 @default.
- W2018553833 hasConcept C155647269 @default.
- W2018553833 hasConcept C161790260 @default.
- W2018553833 hasConcept C163638829 @default.
- W2018553833 hasConcept C178516000 @default.
- W2018553833 hasConcept C178790620 @default.
- W2018553833 hasConcept C185592680 @default.
- W2018553833 hasConceptScore W2018553833C115624301 @default.
- W2018553833 hasConceptScore W2018553833C145148216 @default.
- W2018553833 hasConceptScore W2018553833C155647269 @default.
- W2018553833 hasConceptScore W2018553833C161790260 @default.
- W2018553833 hasConceptScore W2018553833C163638829 @default.
- W2018553833 hasConceptScore W2018553833C178516000 @default.
- W2018553833 hasConceptScore W2018553833C178790620 @default.
- W2018553833 hasConceptScore W2018553833C185592680 @default.
- W2018553833 hasIssue "1-2" @default.
- W2018553833 hasLocation W20185538331 @default.
- W2018553833 hasOpenAccess W2018553833 @default.
- W2018553833 hasPrimaryLocation W20185538331 @default.
- W2018553833 hasRelatedWork W1979228601 @default.
- W2018553833 hasRelatedWork W2066352345 @default.
- W2018553833 hasRelatedWork W2080778007 @default.
- W2018553833 hasRelatedWork W2083800882 @default.
- W2018553833 hasRelatedWork W2086749303 @default.
- W2018553833 hasRelatedWork W2949516606 @default.
- W2018553833 hasRelatedWork W2949733169 @default.
- W2018553833 hasRelatedWork W2950975728 @default.
- W2018553833 hasRelatedWork W2951015813 @default.
- W2018553833 hasRelatedWork W2951636420 @default.
- W2018553833 hasVolume "506" @default.