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• W2018562309 abstract "Abstract The trans -[RuCl 2 (dppb)(1,4-dt)], mer -[RuCl 3 (dppb)(1,4-dt)] and [{RuCl 3 (dppb)} 2 (μ-(1,4-dt))] complexes were synthesized and characterized by spectroscopic and electrochemical techniques. Despite the favorable energy for the C 2 h conformation, the crystallographic data point for the 1,4-dithiane (1,4-dt) D 2 conformer in the trans -[RuCl 2 (dppb)(1,4-dt)] complex, where it acts as a bidentate ligand. The E 1/2 value of this complex is higher than those found for some related pyridine derivative compounds showing that with this thio-ligand, the Ru(II) atom presents a relatively strong π back-bonding interaction. Apart from the phosphine intraligand transitions, the UV/Vis spectrum of the trans- [RuCl 2 (dppb)(1,4-dt)] complex shows only one band at 457 nm assigned to the MLCT transition. The bands observed in the spectra of the mer -[RuCl 3 (dppb)(1,4-dt)] and [{RuCl 3 (dppb)} 2 (μ-(1,4-dt))] complexes, at 530, 420 and 347 nm were attributed to the contribution of the (Ru III ) ← (Cl,S) LMCT transitions. The EPR spectrum of the mer -[RuCl 3 (dppb)(1,4-dt)] complex shows three g -values in 2.87, 2.15 and 1.73, suggesting that the 1,4-dt is coordinated in a monodentate mode. The NMR, EPR, FTIR and crystallographic data point for the ruthenium-phosphine species as the first example of metallic system that form complexes with the 1,4-dithiane acting as bidentate, monodentate and bridged ligand." @default.
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• W2018562309 date "2006-05-01" @default.
• W2018562309 modified "2023-09-24" @default.
• W2018562309 title "The versatility of the 1,4-dithiane ligand towards the coordination chemistry of ruthenium-phosphine complexes" @default.
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• W2018562309 doi "https://doi.org/10.1016/j.poly.2005.10.012" @default.
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