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- W2018575237 abstract "Abstract The conventional explanation of the density augmentation in a supercritical solvent, observed spectroscopically when a small amount of a solute was added, involved the clustering of the solvent about individual solute molecules. Here it is suggested that the augmentation is not caused by the solute, but rather it is due to the preexisting near critical fluctuations in the pure solvent and the preference of the solute for the high density regions of the supercritical solvent. It is also shown that the local composition of the solute molecules about a solute molecules is enhanced compared to its bulk composition." @default.
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- W2018575237 date "2000-11-01" @default.
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- W2018575237 title "Why density augmentation occurs in dilute supercritical solutions" @default.
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