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- W2018587402 abstract "Negatively-charged clusters of carbon dioxide, (CO2)n-, react with NO to form anions with [(CO2)m(NO)]− stoichiometry. The chemical identity of [(CO2)m(NO)]− is probed by photoelectron spectroscopy; the vertical detachment energy of the smallest product anion, [(CO2)(NO)]−, is determined to be 3.72 ± 0.04 eV. With the aid of ab initio calculations, [(CO2)(NO)]− is further identified as O2CNO−(1A′) having a covalent C–N linkage between the CO2 and NO units. These findings demonstrate that (1) (CO2)n- behaves as a CO2- radical anion in the gas-phase chemistry, and that (2) the relevant reaction proceeds as a radical addition process, CO2-+NO→O2CNO-(1A′)." @default.
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- W2018587402 date "2006-12-01" @default.
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- W2018587402 title "Formation of O2CNO− in the reaction of <mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML altimg=si3.gif display=inline overflow=scroll><mml:mrow><mml:mo stretchy=false>(</mml:mo><mml:msub><mml:mrow><mml:mtext>CO</mml:mtext></mml:mrow><mml:mrow><mml:mn>2</mml:mn></mml:mrow></mml:msub><mml:msubsup><mml:mrow><mml:mo stretchy=false>)</mml:mo></mml:mrow><mml:mrow><mml:mi>n</mml:mi></mml:mrow><mml:mrow><mml:mo>-</mml:mo></mml:mrow></mml:msubsup></mml:mrow></mml:math> with NO" @default.
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- W2018587402 doi "https://doi.org/10.1016/j.cplett.2006.11.011" @default.
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