Matches in SemOpenAlex for { <https://semopenalex.org/work/W2018596064> ?p ?o ?g. }
Showing items 1 to 82 of
82
with 100 items per page.
- W2018596064 endingPage "807" @default.
- W2018596064 startingPage "798" @default.
- W2018596064 abstract "The microwave spectrum of the mono-deuterated phosphine (P${mathrm{H}}_{2}$D), arsine (As${mathrm{H}}_{2}$D), and stibine (Sb${mathrm{H}}_{2}$D) has been measured. Although a supposedly pure sample of stibine was prepared, phosphine and arsine proved to be major impurities. They were separated from the sample; the microwave spectrometer was used to monitor the distillation process. The quadrupole fine structure associated with the absorption transitions for As${mathrm{H}}_{2}$D is used to illustrate the special assumptions which may be made with these molecules having an axis of charge symmetry. These assumptions allow one to rotate the coordinate system from the chargesymmetry axes to the inertial axes without thereby adding unknown cross derivatives to the descriptions of the dyadic $ensuremath{nabla}{E}_{mathrm{zz}}$. Interpretation of the spectrum of Sb${mathrm{H}}_{2}$D is more complicated. It is not found possible to fit the theory to the observed lines without making use of the second-order perturbations caused by a nearby level of different symmetry but of the same $J$. This perturbation involves the cross derivatives which had previously been assumed to be zero. With the assumption of cross derivatives approximately one percent of the diagonal terms, the theory fitted experiment within the experimental error. The electric quadrupole interaction in arsine and stibine is thus determined.In order to measure the electric dipole moment of arsine and stibine, a slight extension is made to the theory of asymmetric tops in a uniform electric field.The ground-state inversion splitting is determined to be less than 0.5 Mc/sec for all three molecules.The rotational transitions observed were such that a determination of the structure of these three molecules is made." @default.
- W2018596064 created "2016-06-24" @default.
- W2018596064 creator A5021942895 @default.
- W2018596064 creator A5075144426 @default.
- W2018596064 date "1951-03-01" @default.
- W2018596064 modified "2023-10-18" @default.
- W2018596064 title "Microwave Spectrum of Phosphine, Arsine, and Stibine" @default.
- W2018596064 cites W1625263943 @default.
- W2018596064 cites W1980287924 @default.
- W2018596064 cites W1984314410 @default.
- W2018596064 cites W1991525535 @default.
- W2018596064 cites W2006610074 @default.
- W2018596064 cites W2023150506 @default.
- W2018596064 cites W2025367838 @default.
- W2018596064 cites W2031125853 @default.
- W2018596064 cites W2033844788 @default.
- W2018596064 cites W2044740435 @default.
- W2018596064 cites W2054942956 @default.
- W2018596064 cites W2056239332 @default.
- W2018596064 cites W2067544872 @default.
- W2018596064 cites W2070140401 @default.
- W2018596064 cites W2080738544 @default.
- W2018596064 cites W2080807000 @default.
- W2018596064 cites W2108287225 @default.
- W2018596064 cites W2299877719 @default.
- W2018596064 cites W2312487533 @default.
- W2018596064 cites W2486179406 @default.
- W2018596064 doi "https://doi.org/10.1103/physrev.81.798" @default.
- W2018596064 hasPublicationYear "1951" @default.
- W2018596064 type Work @default.
- W2018596064 sameAs 2018596064 @default.
- W2018596064 citedByCount "74" @default.
- W2018596064 countsByYear W20185960642013 @default.
- W2018596064 countsByYear W20185960642014 @default.
- W2018596064 countsByYear W20185960642017 @default.
- W2018596064 countsByYear W20185960642018 @default.
- W2018596064 countsByYear W20185960642021 @default.
- W2018596064 crossrefType "journal-article" @default.
- W2018596064 hasAuthorship W2018596064A5021942895 @default.
- W2018596064 hasAuthorship W2018596064A5075144426 @default.
- W2018596064 hasBestOaLocation W20185960642 @default.
- W2018596064 hasConcept C121332964 @default.
- W2018596064 hasConcept C161790260 @default.
- W2018596064 hasConcept C184779094 @default.
- W2018596064 hasConcept C185592680 @default.
- W2018596064 hasConcept C2776776902 @default.
- W2018596064 hasConcept C2777039156 @default.
- W2018596064 hasConcept C2777716191 @default.
- W2018596064 hasConcept C39984356 @default.
- W2018596064 hasConcept C55493867 @default.
- W2018596064 hasConceptScore W2018596064C121332964 @default.
- W2018596064 hasConceptScore W2018596064C161790260 @default.
- W2018596064 hasConceptScore W2018596064C184779094 @default.
- W2018596064 hasConceptScore W2018596064C185592680 @default.
- W2018596064 hasConceptScore W2018596064C2776776902 @default.
- W2018596064 hasConceptScore W2018596064C2777039156 @default.
- W2018596064 hasConceptScore W2018596064C2777716191 @default.
- W2018596064 hasConceptScore W2018596064C39984356 @default.
- W2018596064 hasConceptScore W2018596064C55493867 @default.
- W2018596064 hasIssue "5" @default.
- W2018596064 hasLocation W20185960641 @default.
- W2018596064 hasLocation W20185960642 @default.
- W2018596064 hasLocation W20185960643 @default.
- W2018596064 hasOpenAccess W2018596064 @default.
- W2018596064 hasPrimaryLocation W20185960641 @default.
- W2018596064 hasRelatedWork W1966884444 @default.
- W2018596064 hasRelatedWork W1980798886 @default.
- W2018596064 hasRelatedWork W2002517614 @default.
- W2018596064 hasRelatedWork W2021870645 @default.
- W2018596064 hasRelatedWork W2033698721 @default.
- W2018596064 hasRelatedWork W2044557635 @default.
- W2018596064 hasRelatedWork W2107209968 @default.
- W2018596064 hasRelatedWork W2148646004 @default.
- W2018596064 hasRelatedWork W2951779169 @default.
- W2018596064 hasRelatedWork W2952701982 @default.
- W2018596064 hasVolume "81" @default.
- W2018596064 isParatext "false" @default.
- W2018596064 isRetracted "false" @default.
- W2018596064 magId "2018596064" @default.
- W2018596064 workType "article" @default.