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- W2018600928 abstract "Superhydrophobic and oleophobic rough copolymer surfaces containing micro- and nano-hierarchical ball-like islands having diameters between 100 nm and 7 μm were formed using styrene-perfluoromethacrylate random copolymers which were dip-coated on glass slides from THF and MEK mixture containing methanol as nonsolvent. These copolymers were synthesized in a CO2-expanded monomer medium at 250 bar pressure and 80 °C. The sizes of the micro-islands can be controlled by varying the copolymer composition; and the degree of phase separation by adjusting the solvent/non-solvent ratio. Flat and lotus-like hierarchical surfaces of the copolymers were characterized using contact angle measurements and SEM. The increase in the perfluoromethacrylate content of the flat copolymers resulted in a decrease of the total surface free energy of the flat copolymer surfaces from 18.3 down to 14.2 mJ/m2. The increase in the methanol non-solvent fraction resulted in decrease of the micro-island diameter from 7 μm down to 100 nm and the water contact angle increased from 117° up to 160° and hexadecane from 65° up to 90°." @default.
- W2018600928 created "2016-06-24" @default.
- W2018600928 creator A5060429935 @default.
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- W2018600928 date "2014-02-01" @default.
- W2018600928 modified "2023-09-25" @default.
- W2018600928 title "Superhydrophobic perfluoropolymer surfaces having heterogeneous roughness created by dip-coating from solutions containing a nonsolvent" @default.
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- W2018600928 doi "https://doi.org/10.1016/j.apsusc.2013.12.013" @default.
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