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• W2018601981 abstract "X‐ray and γ‐ray irradiation of benzene solutions of cis‐ or trans‐stilbene causes interconversion towards a stationary cis→trans mixture. The yield of interconversion is smaller for cis→trans than for trans→cis. Both yields increase with stilbene concentration up to a limiting G(trans→cis) of about 2.5 at 0.1M, which corresponds to G(excited stilbene) of about 5. At low stilbene concentrations the yield is lowered by oxygen and by anthracene and enhanced by naphthalene, triphenylene, phenanthrene, and diphenyl. Diacetyl and p‐terphenyl preferentially enhance the trans→cis conversion. The results are explained on the basis of primary excitation of solvent benzene which forms excited stilbene by energy transfer, as in photosensitized isomerization. Direct excitation and possibly charge recombination may account for the primary solvent excitation. Enhancement by additives is due to energy transfer from excited benzene to form eventually triplet additive, which, owing to its much longer lifetime, has a greatl..." @default.
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• W2018601981 date "1966-12-01" @default.
• W2018601981 modified "2023-09-26" @default.
• W2018601981 title "X‐ and γ‐Ray‐Induced Radiolytic Isomerization of Solutions of Stilbene" @default.
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• W2018601981 doi "https://doi.org/10.1063/1.1727436" @default.
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