Matches in SemOpenAlex for { <https://semopenalex.org/work/W2018605800> ?p ?o ?g. }
- W2018605800 endingPage "7513" @default.
- W2018605800 startingPage "7513" @default.
- W2018605800 abstract "The hydrido complexes trans-[Pd(H)(4-C(5)NF(4))(PiPr(3))(2)] (3) and trans-[Pd(H)(4-C(5)NF(4))(PCy(3))(2)] (5) can be prepared by reaction of trans-[Pd(F)(4-C(5)NF(4))(PiPr(3))(2)] (2) or trans-[Pd(F)(4-C(5)NF(4))(PCy(3))(2)] (4) with HBpin (HBpin = 4,4,5,5-tetramethyl-1,3,2-dioxaborolane, pinacolborane). The iodo and triflato complexes trans-[Pd(I)(4-C(5)NF(4))(PiPr(3))(2)] (7) and trans-[Pd(OTf)(4-C(5)NF(4))(PiPr(3))(2)] (9) are generated on treatment of complex 3 with MeI or ethyltrifluoromethanesulfonate (EtOTf), respectively. Treatment of 3 with Ph(3)CPF(6) in MeCN results in the formation of trans-[Pd(4-C(5)NF(4))(NCMe)(PiPr(3))(2)]PF(6) (6a). Heating 3 to 60 degrees C gives the products of reductive elimination 2,3,5,6-tetrafluoropyridine as well as [Pd(PiPr(3))(2)] (1). In the presence of pentafluoropyridine [Pd(PiPr(3))(2)] (1) affords the oxidative addition product 2. In a catalytic experiment, pentafluoropyridine can be converted into 2,3,5,6-tetrafluoropyridine in the presence of HBpin with 44% yield when 10% of 3 is employed as catalyst." @default.
- W2018605800 created "2016-06-24" @default.
- W2018605800 creator A5038277232 @default.
- W2018605800 creator A5088494920 @default.
- W2018605800 creator A5019166063 @default.
- W2018605800 date "2010-01-01" @default.
- W2018605800 modified "2023-09-25" @default.
- W2018605800 title "Isolation and reactivity of palladium hydrido complexes: intermediates in the hydrodefluorination of pentafluoropyridine" @default.
- W2018605800 cites W1498567115 @default.
- W2018605800 cites W1689512864 @default.
- W2018605800 cites W1953015072 @default.
- W2018605800 cites W1966219336 @default.
- W2018605800 cites W1966469919 @default.
- W2018605800 cites W1968675528 @default.
- W2018605800 cites W1970398191 @default.
- W2018605800 cites W1973995017 @default.
- W2018605800 cites W1974292995 @default.
- W2018605800 cites W1975254007 @default.
- W2018605800 cites W1976708451 @default.
- W2018605800 cites W1978694618 @default.
- W2018605800 cites W1978901513 @default.
- W2018605800 cites W1981224872 @default.
- W2018605800 cites W1981648978 @default.
- W2018605800 cites W1982251590 @default.
- W2018605800 cites W1983182954 @default.
- W2018605800 cites W1983216506 @default.
- W2018605800 cites W1983401069 @default.
- W2018605800 cites W1984625169 @default.
- W2018605800 cites W1985037036 @default.
- W2018605800 cites W1986359076 @default.
- W2018605800 cites W1986757319 @default.
- W2018605800 cites W1988919832 @default.
- W2018605800 cites W1992124690 @default.
- W2018605800 cites W1992748264 @default.
- W2018605800 cites W1994601992 @default.
- W2018605800 cites W1996179594 @default.
- W2018605800 cites W1997693693 @default.
- W2018605800 cites W1997764401 @default.
- W2018605800 cites W1998453547 @default.
- W2018605800 cites W1999859373 @default.
- W2018605800 cites W2000278166 @default.
- W2018605800 cites W2001078155 @default.
- W2018605800 cites W2001142168 @default.
- W2018605800 cites W2002904039 @default.
- W2018605800 cites W2003810621 @default.
- W2018605800 cites W2006647889 @default.
- W2018605800 cites W2006854140 @default.
- W2018605800 cites W2009402694 @default.
- W2018605800 cites W2010472723 @default.
- W2018605800 cites W2011618667 @default.
- W2018605800 cites W2012231656 @default.
- W2018605800 cites W2012404887 @default.
- W2018605800 cites W2013044080 @default.
- W2018605800 cites W2013686593 @default.
- W2018605800 cites W2015397928 @default.
- W2018605800 cites W2016028459 @default.
- W2018605800 cites W2019603019 @default.
- W2018605800 cites W2019886099 @default.
- W2018605800 cites W2021376891 @default.
- W2018605800 cites W2024783647 @default.
- W2018605800 cites W2025038929 @default.
- W2018605800 cites W2026262620 @default.
- W2018605800 cites W2029739392 @default.
- W2018605800 cites W2030752547 @default.
- W2018605800 cites W2032571285 @default.
- W2018605800 cites W2035823468 @default.
- W2018605800 cites W2040079056 @default.
- W2018605800 cites W2040454689 @default.
- W2018605800 cites W2040822521 @default.
- W2018605800 cites W2041201684 @default.
- W2018605800 cites W2042431246 @default.
- W2018605800 cites W2046179621 @default.
- W2018605800 cites W2046857241 @default.
- W2018605800 cites W2050285882 @default.
- W2018605800 cites W2051657825 @default.
- W2018605800 cites W2055069218 @default.
- W2018605800 cites W2062566916 @default.
- W2018605800 cites W2063098086 @default.
- W2018605800 cites W2063698579 @default.
- W2018605800 cites W2063821794 @default.
- W2018605800 cites W2065972736 @default.
- W2018605800 cites W2074100780 @default.
- W2018605800 cites W2077282142 @default.
- W2018605800 cites W2077871823 @default.
- W2018605800 cites W2079702769 @default.
- W2018605800 cites W2084897334 @default.
- W2018605800 cites W2085925264 @default.
- W2018605800 cites W2086997732 @default.
- W2018605800 cites W2089144694 @default.
- W2018605800 cites W2089275640 @default.
- W2018605800 cites W2095986148 @default.
- W2018605800 cites W2099741635 @default.
- W2018605800 cites W2116328800 @default.
- W2018605800 cites W2119405370 @default.
- W2018605800 cites W2119778173 @default.
- W2018605800 cites W2121245336 @default.
- W2018605800 cites W2121835375 @default.
- W2018605800 cites W2124968436 @default.