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- W2018658744 abstract "Abstract The structure of poly(diethylsilylenemethylene) (PDESM), poly(di-n-butylsilylenemethylene) (PDBSM), poly(di-n-pentylsilylenemethylene) (PDPeSM) and poly(di-n-hexylsilylenemethylene) (PDHSM) have been studied using X-ray and electron diffraction methods. The structure of poly(di-n-propylsilylenemethylene) (PDPrSM) has been studied and reported in a separate paper. PDBSM, PDPrSM, PDPeSM and PDHSM all have similar packing with a two dimensional monoclinic ab-projection of the unit cell. PDESM with the shortest alkyl side chain, has a nearly orthorhombic unit cell (γ ∗ =∼88°) containing two chains (four repeat units), one at the corner and the second nearly in the center of the ab-projection of the unit cell. The backbone conformation of each of these polysilylenemethylenes (PSMs) is all-gauche, giving them a 41 helical structure. The length of the alkyl side chains affects the packing without changing the backbone conformation." @default.
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- W2018658744 date "2001-04-01" @default.
- W2018658744 modified "2023-09-25" @default.
- W2018658744 title "The structures of poly(di-n-alkylsilylenemethylene)s" @default.
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- W2018658744 doi "https://doi.org/10.1016/s0032-3861(00)00772-2" @default.
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