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- W2018671714 abstract "The ethylene complex Cp2Zr(C2H4)(PMe3) (1) reacts readily with a variety of substrates: alcohols ROH (R Me, Et, Ph) give the alkoxy ethyl complexes Cp2Zr(Et)(OR), the mercaptan tBuSH gives the thiolate ethyl complex Cp2Zr(Et)(StBu), water gives the dinuclear oxo-bridged complex [Cp2Zr(Et)]2μ-O, and the acids HX (X Cl, H(O)CO, and the CH3(O)CO, CF3(O)CO) give the complexes Cp2Zr(Et)X and Cp2ZrX2. The reaction of Cp2Zr(Et)[OC(O)H] with water gives the dinuclear Cp2Zr[OC(O)H]2μ-O. Cp2Zr(Et)(StBu) reacts with HX (X H(O)CO, CH3(O)CO) and ROH to yield the carboxylate ethyl complexes Cp2Zr(Et)X and the alkoxy ethyl complexes Cp2Zr(Et)(OR). Der Ethylenkomplex Cp2Zr(C2H4)(PMe3) (1) reagiert bereitwillig mit einer Reihe von Substraten: mit Alkoholen ROH (R Me, Et, Ph) entstehen die Alkoxy-Ethylkomplexe Cp2Zr(Et)(OR), mit dem Mercaptan tBuSH der Thiolat-Ethylkomplex Cp2Zr(Et)(StBu), mit Wasser der Oxo-verbrückte Zweikernkomplex [Cp2Zr(Et)]2μ-O, mit Säuren HX (X Cl, H(O)CO, CH3(O)CO, CF3(O)CO) die Komplexe Cp2Zr(Et)X und Cp2ZrX2. Cp2Zr(Et)[OC(O)H] reagiert mit Wasser zum zweikernigen Komplex Cp2Zr[OC(O)H]2μ-O, Cp2Zr(Et)(StBu) mit HX bzw. ROH zum Carboxylat-Ethylkomplex Cp2Zr(Et)X bzw. zum Alkoxy-Ethylkomplex Cp2Zr(Et)(OR)." @default.
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- W2018671714 date "1990-07-01" @default.
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- W2018671714 title "Ethylkomplexe des zirkonocens" @default.
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- W2018671714 doi "https://doi.org/10.1016/0022-328x(90)80156-t" @default.
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