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• W2018672077 abstract "A new set-up for conducting differential electrochemical mass spectroscopy (DEMS) analysis at temperatures between 120 and 180 °C is presented. It enables the characterization and testing of model electrodes in a three electrode assembly under experimental conditions close to those in a high temperature proton exchange membrane fuel cell (HT-PEMFC). This is of special interest for the study of the degradation of fuel cell materials as well as the electro-oxidation reactions of small organic molecules used in direct alcohol fuel cells (DAFCs). While other DEMS set-ups only allow for studying reactions occurring in a liquid electrolyte, the HT-DEMS set-up makes it possible to study reactions in the gas phase. The design of the set-up is presented. Cyclic voltammetry (CV) measurements at 150 °C were carried out on Pt/C and Pt black catalysts under nitrogen atmosphere. Oxidation of adsorbed CO and bulk oxidation of ethanol were performed on Pt/C." @default.
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• W2018672077 date "2015-06-01" @default.
• W2018672077 modified "2023-10-14" @default.
• W2018672077 title "Development of a novel experimental DEMS set-up for electrocatalyst characterization under working conditions of high temperature polymer electrolyte fuel cells" @default.
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• W2018672077 doi "https://doi.org/10.1016/j.jelechem.2015.04.002" @default.
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