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• W2018694517 abstract "Triphenyltin hydroxide condenses with 4,5-dimethylisothiazol-3(2H)-one 1,1-dioxide in the presence of one equivalent of diphenylcyclopropenone in ethanol to give (C6H5)3SnOCNS(O2)C(CH3CCH3·OCC(C6H5)CC6H5. In the adduct the cyclic ketone (CO = 1.245(3) Å) is linked coordinately (Sn ← O = 2.372(2) Å; Sn ← OC = 122.7(2)°C) to the Lewis acid (SnO = 2.164(2),Å). The geometry of the tin atom is trans-trigonal bipyramidal (OSn ← O = 178.5(1)°; ΣCSnC = 357.7(3)°). Triphenyltin hydroxide reacts with saccharin and diphenylcyclopropenone in ethanol to give the isostructural (C6H5)3SnOCNS(O2)C6H4·OCC(C6H5)-CC6H5 complex. Selected bond distances and angles in this complex are: SnO = 2.164(3), Sn ← O = 2.421(3), CO = 1.230 (4) Å, Sn ← OC = 129.3(2)°; OSN ← O = 173.2(1)°; ΣCSnC = 358.5(3)°." @default.
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• W2018694517 title "Crystal structures of the 1/1 adducts of diphenylcyclopropenone with 3-triphenylstannyloxy-4,5-dimethylisothiazole 1,1-dioxide and 3-triphenylstannyloxybenzisothiazole 1,1-dioxide" @default.
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• W2018694517 doi "https://doi.org/10.1016/0022-328x(93)80424-a" @default.
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