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• W2018697744 abstract "Reduction of MR2Cl, M  Al or Ga, R = 2-C(SiMe3)2C5H4N, in THF yields the paramagnetic dialkylmetal species, [MR2]., which in the absence of solvent yields diamagnetic material shown to contain reductively coupled pyridyl groups by isolation of the corresponding 4,4′-dipyridyl after hydrolysis and oxidation. An X-ray diffraction study of [GaR2Cl] has shown the metal to be in a distorted trigonal bipyramidal environment with apical N-centres." @default.
• W2018697744 created "2016-06-24" @default.
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• W2018697744 date "1990-02-01" @default.
• W2018697744 modified "2023-09-27" @default.
• W2018697744 title "Solution stabilized monomeric dialkyl-aluminium and -gallium species, [MR2]. (R = 2-C(SiMe3)2C5H4N): from reduction of MR2Cl. Crystal structure of GaR2Cl" @default.
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• W2018697744 doi "https://doi.org/10.1016/0022-328x(90)87072-l" @default.
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