FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2018712769> ?p ?o ?g. }

• W2018712769 endingPage "1029" @default.
• W2018712769 startingPage "1023" @default.
• W2018712769 abstract "This paper describes the development of a sequential injection analysis method to automate the determination of picloram by square wave voltammetry exploiting the concept of monosegmented flow analysis to perform in-line sample conditioning and standard addition. To perform these tasks, an 800muL monosegment is formed, composed by 400muL of sample and 400muL of conditioning/standard solution, in medium of 0.10molL(-1) H(2)SO(4). Homogenization of the monosegment is achieved by three flow reversals. After homogenization the mixture zone is injected toward the flow cell, which is adapted to the capillary of a hanging drop mercury electrode, at a flow rate of 50muLs(-1). After a suitable delay time, the potential is scanned from -0.5 to -1.0V versus Ag/AgCl at frequency of 300Hz and pulse height of 25mV. The linear dynamic range is observed for picloram concentrations between 0.10 and 2.50mgL(-1) fitting to the linear equation I(p)=(-2.19+/-0.03)C(picloram)+(0.096+/-0.039), with R(2)=0.9996, for which the slope is given in muALmg(-1). The detection and quantification limits are 0.036 and 0.12mgL(-1), respectively. The sampling frequency is 37h(-1) when the standard addition protocol is followed, but can be increased to 41h(-1) if the protocol to obtain in-line external calibration curve is used for quantification. The method was applied for determination of picloram in spiked water samples and the accuracy was evaluated by comparison with high performance liquid chromatography using molecular absorption at 220nm for detection. No evidences of statistically significant differences between the two methods were observed." @default.
• W2018712769 created "2016-06-24" @default.
• W2018712769 creator A5055694076 @default.
• W2018712769 creator A5090140538 @default.
• W2018712769 date "2007-05-15" @default.
• W2018712769 modified "2023-10-07" @default.
• W2018712769 title "Determination of picloram in natural waters employing sequential injection square wave voltammetry using the hanging mercury drop electrode" @default.
• W2018712769 cites W150169156 @default.
• W2018712769 cites W1981991919 @default.
• W2018712769 cites W1985128862 @default.
• W2018712769 cites W1990493696 @default.
• W2018712769 cites W2022769611 @default.
• W2018712769 cites W2029965690 @default.
• W2018712769 cites W2031470815 @default.
• W2018712769 cites W2032521337 @default.
• W2018712769 cites W2034676353 @default.
• W2018712769 cites W2035151912 @default.
• W2018712769 cites W2038822432 @default.
• W2018712769 cites W2040079588 @default.
• W2018712769 cites W2041054301 @default.
• W2018712769 cites W2049595812 @default.
• W2018712769 cites W2049960072 @default.
• W2018712769 cites W2050097096 @default.
• W2018712769 cites W2055590630 @default.
• W2018712769 cites W2059376073 @default.
• W2018712769 cites W2064191643 @default.
• W2018712769 cites W2065459986 @default.
• W2018712769 cites W2076800751 @default.
• W2018712769 cites W2093060781 @default.
• W2018712769 cites W2130004951 @default.
• W2018712769 cites W2145934145 @default.
• W2018712769 cites W2146603130 @default.
• W2018712769 cites W2158399008 @default.
• W2018712769 cites W2164952060 @default.
• W2018712769 cites W2943693362 @default.
• W2018712769 cites W651954035 @default.
• W2018712769 cites W2016827855 @default.
• W2018712769 cites W2042881853 @default.
• W2018712769 cites W2140376800 @default.
• W2018712769 doi "https://doi.org/10.1016/j.talanta.2006.12.030" @default.
• W2018712769 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/19071719" @default.
• W2018712769 hasPublicationYear "2007" @default.
• W2018712769 type Work @default.
• W2018712769 sameAs 2018712769 @default.
• W2018712769 citedByCount "30" @default.
• W2018712769 countsByYear W20187127692012 @default.
• W2018712769 countsByYear W20187127692013 @default.
• W2018712769 countsByYear W20187127692014 @default.
• W2018712769 countsByYear W20187127692015 @default.
• W2018712769 countsByYear W20187127692016 @default.
• W2018712769 countsByYear W20187127692018 @default.
• W2018712769 countsByYear W20187127692020 @default.
• W2018712769 countsByYear W20187127692021 @default.
• W2018712769 countsByYear W20187127692023 @default.
• W2018712769 crossrefType "journal-article" @default.
• W2018712769 hasAuthorship W2018712769A5055694076 @default.
• W2018712769 hasAuthorship W2018712769A5090140538 @default.
• W2018712769 hasConcept C113196181 @default.
• W2018712769 hasConcept C119128265 @default.
• W2018712769 hasConcept C121332964 @default.
• W2018712769 hasConcept C147789679 @default.
• W2018712769 hasConcept C165801399 @default.
• W2018712769 hasConcept C17525397 @default.
• W2018712769 hasConcept C185592680 @default.
• W2018712769 hasConcept C199360897 @default.
• W2018712769 hasConcept C23531484 @default.
• W2018712769 hasConcept C2353230 @default.
• W2018712769 hasConcept C2776278163 @default.
• W2018712769 hasConcept C2777777548 @default.
• W2018712769 hasConcept C2779603750 @default.
• W2018712769 hasConcept C41008148 @default.
• W2018712769 hasConcept C43617362 @default.
• W2018712769 hasConcept C52859227 @default.
• W2018712769 hasConcept C62520636 @default.
• W2018712769 hasConcept C77170095 @default.
• W2018712769 hasConcept C96352100 @default.
• W2018712769 hasConceptScore W2018712769C113196181 @default.
• W2018712769 hasConceptScore W2018712769C119128265 @default.
• W2018712769 hasConceptScore W2018712769C121332964 @default.
• W2018712769 hasConceptScore W2018712769C147789679 @default.
• W2018712769 hasConceptScore W2018712769C165801399 @default.
• W2018712769 hasConceptScore W2018712769C17525397 @default.
• W2018712769 hasConceptScore W2018712769C185592680 @default.
• W2018712769 hasConceptScore W2018712769C199360897 @default.
• W2018712769 hasConceptScore W2018712769C23531484 @default.
• W2018712769 hasConceptScore W2018712769C2353230 @default.
• W2018712769 hasConceptScore W2018712769C2776278163 @default.
• W2018712769 hasConceptScore W2018712769C2777777548 @default.
• W2018712769 hasConceptScore W2018712769C2779603750 @default.
• W2018712769 hasConceptScore W2018712769C41008148 @default.
• W2018712769 hasConceptScore W2018712769C43617362 @default.
• W2018712769 hasConceptScore W2018712769C52859227 @default.
• W2018712769 hasConceptScore W2018712769C62520636 @default.
• W2018712769 hasConceptScore W2018712769C77170095 @default.
• W2018712769 hasConceptScore W2018712769C96352100 @default.
• W2018712769 hasIssue "3" @default.
• W2018712769 hasLocation W20187127691 @default.
• W2018712769 hasLocation W20187127692 @default.

• next