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- W2018722078 abstract "We have previously demonstrated the efficiency of CO and SO2 surface treatments for the stabilization of the LaNi5 hydride. The as-treated hydrides were stable in air at room temperature. Here, CO surface treatment is applied to higher dissociation pressure systems, La1−xCexNi5 (x=0, 0.1, 0.2 and 0.3) compounds. Stabilization of the hydrides is studied at two temperatures, 273 and 298 K. We found that the hydrogen retention time for CO-treated La1−xCexNi5 hydrides is dramatically improved compared with that of untreated hydrides. Nevertheless, for both temperatures, the hydrogen retention time in treated hydrides is found to decrease with increasing cerium content. The results are explained on the basis of P–C–T measurements carried out at room temperature. As expected, the hydrogen absorption and desorption pressures and the hysteresis increase with cerium content. The dehydrogenation kinetics of CO-treated hydrides is related to the cerium content of the alloys." @default.
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- W2018722078 date "1998-07-01" @default.
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- W2018722078 title "Stabilisation of high dissociation pressure hydrides of formula La1−Ce Ni5 (x=0–0.3) with carbon monoxide" @default.
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- W2018722078 doi "https://doi.org/10.1016/s0925-8388(98)00283-7" @default.
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