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- W2018746776 abstract "Different Schrock-type molybdenum carbene complexes with hexafluoroalkoxy-ligands were examined for their suitability for the acyclic diene metathesis (ADMET) polycondensation of 2,5-dialkyl-1,4-divinylbenzenes (DRDVB). Kinetic studies on cross-metathesis showed that catalysts with (2,6-dimethylphenyl)imido ligands are the most active. 1H-NMR investigations of the reaction of 2,5-diheptyl-1,4-divinylbenzene using Mo(NArMe2)(CHC(Me)2Ph)(OC(Me)(CF3)2)2 as catalyst show the in situ formation of a new carbene species as well as molybdenacyclobutane intermediate." @default.
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- W2018746776 date "1997-01-01" @default.
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- W2018746776 title "Investigations of stable molybdenum carbene complexes for the metathesis synthesis of dialkylsubstituted poly(p-phenylenevinylene)s (PPVs)" @default.
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- W2018746776 doi "https://doi.org/10.1016/s1381-1169(96)00079-9" @default.
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