Matches in SemOpenAlex for { <https://semopenalex.org/work/W2018749505> ?p ?o ?g. }
- W2018749505 endingPage "547" @default.
- W2018749505 startingPage "537" @default.
- W2018749505 abstract "Abstract A one‐pot cascade reaction for the synthesis of polysubstituted benzofurans and naphthopyrans from simple phenols and propargylic alcohols catalyzed by iron(III) is presented. The results demonstrate that the structural specificity for the formation of furan and pyran products is controlled by the structural nature of the propargylic alcohols. Namely, benzofurans could be synthesized efficiently from phenols and secondary propargylic alcohols in the presence of 5 mol% of iron(III) chloride hexahydrate (FeCl 3 ⋅6 H 2 O) catalyst. On the other hand, pyran derivatives were obtained exclusively when tertiary propargylic alcohols were employed. Mechanistic studies revealed that presumably due to the discriminated steric effect of secondary and tertiary propargylic alcohols, the Fe‐catalyzed Friedel–Crafts (F–C) reaction of phenols with the two types of alcohols proceeds via different models. Most importantly, we have demonstrated for the first time that fully 2,3,4‐substituted naphthopyrans could be synthesized efficiently via the iron‐catalyzed one‐pot cascade reaction. Consequently, the results presented herein provide straightforward pathways for versatile syntheses of valuable benzofuran and pyran derivatives from simple phenolic compounds and propargylic alcohols." @default.
- W2018749505 created "2016-06-24" @default.
- W2018749505 creator A5014679115 @default.
- W2018749505 creator A5054696085 @default.
- W2018749505 date "2013-02-01" @default.
- W2018749505 modified "2023-10-16" @default.
- W2018749505 title "Iron‐Catalyzed Direct Synthesis of Densely Substituted Benzofurans and Naphthopyrans from Phenolic Compounds and Propargylic Alcohols" @default.
- W2018749505 cites W1969455457 @default.
- W2018749505 cites W1969810284 @default.
- W2018749505 cites W1979059400 @default.
- W2018749505 cites W1983666473 @default.
- W2018749505 cites W1989091166 @default.
- W2018749505 cites W1990245027 @default.
- W2018749505 cites W1992242238 @default.
- W2018749505 cites W2002940376 @default.
- W2018749505 cites W2005524060 @default.
- W2018749505 cites W2010895105 @default.
- W2018749505 cites W2013264584 @default.
- W2018749505 cites W2014686354 @default.
- W2018749505 cites W2018310119 @default.
- W2018749505 cites W2019882979 @default.
- W2018749505 cites W2031007547 @default.
- W2018749505 cites W2035122819 @default.
- W2018749505 cites W2038607053 @default.
- W2018749505 cites W2043417884 @default.
- W2018749505 cites W2056030592 @default.
- W2018749505 cites W2067695158 @default.
- W2018749505 cites W2069487319 @default.
- W2018749505 cites W2069805263 @default.
- W2018749505 cites W2070377806 @default.
- W2018749505 cites W2074882630 @default.
- W2018749505 cites W2075339242 @default.
- W2018749505 cites W2081164073 @default.
- W2018749505 cites W2082578254 @default.
- W2018749505 cites W2082788361 @default.
- W2018749505 cites W2095303194 @default.
- W2018749505 cites W2100708161 @default.
- W2018749505 cites W2103554079 @default.
- W2018749505 cites W2105555171 @default.
- W2018749505 cites W2116754127 @default.
- W2018749505 cites W2126363023 @default.
- W2018749505 cites W2135883030 @default.
- W2018749505 cites W2138158145 @default.
- W2018749505 cites W2166458363 @default.
- W2018749505 cites W2166745737 @default.
- W2018749505 cites W2333804822 @default.
- W2018749505 cites W2949672486 @default.
- W2018749505 cites W2952036626 @default.
- W2018749505 cites W2952111351 @default.
- W2018749505 cites W4237407255 @default.
- W2018749505 doi "https://doi.org/10.1002/adsc.201200804" @default.
- W2018749505 hasPublicationYear "2013" @default.
- W2018749505 type Work @default.
- W2018749505 sameAs 2018749505 @default.
- W2018749505 citedByCount "11" @default.
- W2018749505 countsByYear W20187495052013 @default.
- W2018749505 countsByYear W20187495052017 @default.
- W2018749505 countsByYear W20187495052018 @default.
- W2018749505 countsByYear W20187495052019 @default.
- W2018749505 countsByYear W20187495052023 @default.
- W2018749505 crossrefType "journal-article" @default.
- W2018749505 hasAuthorship W2018749505A5014679115 @default.
- W2018749505 hasAuthorship W2018749505A5054696085 @default.
- W2018749505 hasConcept C161790260 @default.
- W2018749505 hasConcept C178790620 @default.
- W2018749505 hasConcept C185592680 @default.
- W2018749505 hasConcept C201194858 @default.
- W2018749505 hasConcept C21951064 @default.
- W2018749505 hasConcept C2776589655 @default.
- W2018749505 hasConcept C2777505907 @default.
- W2018749505 hasConcept C2777728882 @default.
- W2018749505 hasConcept C2778659115 @default.
- W2018749505 hasConcept C2778695967 @default.
- W2018749505 hasConcept C2781066024 @default.
- W2018749505 hasConcept C2909312076 @default.
- W2018749505 hasConceptScore W2018749505C161790260 @default.
- W2018749505 hasConceptScore W2018749505C178790620 @default.
- W2018749505 hasConceptScore W2018749505C185592680 @default.
- W2018749505 hasConceptScore W2018749505C201194858 @default.
- W2018749505 hasConceptScore W2018749505C21951064 @default.
- W2018749505 hasConceptScore W2018749505C2776589655 @default.
- W2018749505 hasConceptScore W2018749505C2777505907 @default.
- W2018749505 hasConceptScore W2018749505C2777728882 @default.
- W2018749505 hasConceptScore W2018749505C2778659115 @default.
- W2018749505 hasConceptScore W2018749505C2778695967 @default.
- W2018749505 hasConceptScore W2018749505C2781066024 @default.
- W2018749505 hasConceptScore W2018749505C2909312076 @default.
- W2018749505 hasIssue "2-3" @default.
- W2018749505 hasLocation W20187495051 @default.
- W2018749505 hasOpenAccess W2018749505 @default.
- W2018749505 hasPrimaryLocation W20187495051 @default.
- W2018749505 hasRelatedWork W1967144082 @default.
- W2018749505 hasRelatedWork W1995351800 @default.
- W2018749505 hasRelatedWork W2021720965 @default.
- W2018749505 hasRelatedWork W2022746333 @default.
- W2018749505 hasRelatedWork W2128717454 @default.
- W2018749505 hasRelatedWork W2312545126 @default.
- W2018749505 hasRelatedWork W2949526114 @default.