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- W2018750357 abstract "The novel group IV metal chelating diamide complexes [(2,6-diisopropylanilido)B(NMe2)B(NMe2)(2,6-diisopropylanilido)]MX2, 7a (M = Ti, X = Cl), 7b (M = Ti, X = Me), and 8 (M = Zr, X = CH2Ph), have been prepared and characterized by 1H and 13C{H} NMR spectroscopy and single-crystal X-ray structure analysis (7a). These complexes are active polymerization catalysts upon combining with the appropriate activator. The catalyst efficiencies, however, are considerably lower than those of Cp-based catalysts. The molecular weights of the polymers produced are activator dependent, and the polydispersities were found to be broader than those observed for Cp-based single-site catalytic systems." @default.
- W2018750357 created "2016-06-24" @default.
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- W2018750357 date "2001-07-06" @default.
- W2018750357 modified "2023-09-24" @default.
- W2018750357 title "Chelating Diamide Group IV Metal Olefin Polymerization Catalysts" @default.
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- W2018750357 doi "https://doi.org/10.1021/om010101l" @default.
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