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• W2018758757 abstract "The use of rotating ring–disk electrodes as generator-collector systems has so far been limited to the detection of Faradaic currents at the ring. As opposed to other generator-collector configurations, non-Faradaic detection has not yet been carried out with rotating ring–disk electrodes. In this study, a.c. perturbation based detection for measurement of the ring impedance is introduced. By using a conducting polymer-modified disk electrode in combination with a bare gold ring as a model, it is shown that the measured ring capacitance correlates with the polarization of the polymer film, most probably due to counter-ion exchange. A method of calculating the ring capacitance based on a small-signal sinusoid perturbation is described and the most important instrumental limitations are identified." @default.
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• W2018758757 date "2015-04-18" @default.
• W2018758757 modified "2023-10-15" @default.
• W2018758757 title "Characterization of the Capacitance of a Rotating Ring–Disk Electrode" @default.
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• W2018758757 doi "https://doi.org/10.1080/10739149.2015.1038561" @default.
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