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- W2018762589 abstract "The adsorption and reaction of C2H2on clean and oxygen covered Ag(110) surfaces was studied with high resolution electron energy loss spectroscopy (EELS). Acetylene adsorbs at 100 K onto the clean surface without rehybridization and desorbs without reaction between 100 and 160 K. Acetylene reacts with adsorbed oxygen atoms at 100 K to form adsorbed CCH and H2O. In contrast to interactions between acetylene and other metals the carbon-carbon triple bond is preserved, as determined by the CH stretching frequency of 3270 cm−1. H2O is displaced from the surface at 100 K, but a small amount (about 5% of a monolayer) remains weakly adsorbed. Unreacted acetylene and the remaining water desorb from 100 to 160 K and from 170 to 200 K, respectively. Although the CC stretching mode was not observed for CCH, the CC bond order was determined to be three from the CH stretching frequency of 3250 cm−1. A model for CCH is proposed with the CC bond nearly parallel to the surface. The CCH formed at low temperatures disproportionates at 280 K to C2H2(g), and CC(a), which in turn dissociates into C(a) at 550 K. The CC(a) species exhibited only one EELS loss at 240 cm−1, whereas no losses were observed for C(a)." @default.
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- W2018762589 date "1982-12-01" @default.
- W2018762589 modified "2023-10-18" @default.
- W2018762589 title "Characterization of the adsorption and reaction of acetylene on clean and oxygen covered Ag(110) by EELS" @default.
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- W2018762589 doi "https://doi.org/10.1016/0039-6028(82)90342-9" @default.
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