Matches in SemOpenAlex for { <https://semopenalex.org/work/W2018773387> ?p ?o ?g. }
- W2018773387 endingPage "16345" @default.
- W2018773387 startingPage "16333" @default.
- W2018773387 abstract "The influence of the support of Pt catalysts for the reaction of steam reforming of ethanol at low temperatures has been investigated on Al2O3, ZrO2 and CeO2. It was found that the conversion of ethanol is significantly higher when Pt is dispersed on Al2O3 or ZrO2, compared to CeO2. Selectivity toward H2 is higher over ZrO2-supported catalyst, which is also able to decrease CO production via the water-gas shift reaction. Depending on catalyst employed, interaction of the reaction mixture with the catalyst surface results in the development of a variety of bands attributed to ethoxy, acetate and formate/carbonate species associated with the support, as well as by bands attributed to carbonyl species adsorbed on platinum sites. The oxidation state of Pt seems to affect catalytic activity, which was found to decrease with increasing the population of adsorbed CO species on partially oxidized (Ptδ+) sites. Evidence is provided that the main reaction pathway ethanol dehydrogenation, through the formation of surface ethoxy species and subsequently acetaldehyde, which is decomposed toward methane, hydrogen and carbon oxides. The population of adsorbed surface species, as well as product distribution in the gas phase varies significantly depending on catalyst reactivity towards the WGS reaction." @default.
- W2018773387 created "2016-06-24" @default.
- W2018773387 creator A5053867045 @default.
- W2018773387 creator A5056679099 @default.
- W2018773387 date "2012-11-01" @default.
- W2018773387 modified "2023-10-12" @default.
- W2018773387 title "Mechanistic aspects of the low temperature steam reforming of ethanol over supported Pt catalysts" @default.
- W2018773387 cites W138805442 @default.
- W2018773387 cites W1594355380 @default.
- W2018773387 cites W1964589612 @default.
- W2018773387 cites W1967451881 @default.
- W2018773387 cites W1968551433 @default.
- W2018773387 cites W1969104275 @default.
- W2018773387 cites W1970811384 @default.
- W2018773387 cites W1971431569 @default.
- W2018773387 cites W1974621302 @default.
- W2018773387 cites W1976116786 @default.
- W2018773387 cites W1977574388 @default.
- W2018773387 cites W1979682724 @default.
- W2018773387 cites W1981001993 @default.
- W2018773387 cites W1984632991 @default.
- W2018773387 cites W1991717299 @default.
- W2018773387 cites W1996390127 @default.
- W2018773387 cites W1997110604 @default.
- W2018773387 cites W2000289532 @default.
- W2018773387 cites W2006965186 @default.
- W2018773387 cites W2009231938 @default.
- W2018773387 cites W2009570116 @default.
- W2018773387 cites W2009724999 @default.
- W2018773387 cites W2009972263 @default.
- W2018773387 cites W2018132715 @default.
- W2018773387 cites W2019237210 @default.
- W2018773387 cites W2020627576 @default.
- W2018773387 cites W2022873561 @default.
- W2018773387 cites W2028753753 @default.
- W2018773387 cites W2032219867 @default.
- W2018773387 cites W2033082093 @default.
- W2018773387 cites W2034573190 @default.
- W2018773387 cites W2036970320 @default.
- W2018773387 cites W2040282442 @default.
- W2018773387 cites W2042225147 @default.
- W2018773387 cites W2043500388 @default.
- W2018773387 cites W2047245781 @default.
- W2018773387 cites W2048836181 @default.
- W2018773387 cites W2054844841 @default.
- W2018773387 cites W2055121871 @default.
- W2018773387 cites W2055599970 @default.
- W2018773387 cites W2055877794 @default.
- W2018773387 cites W2075460637 @default.
- W2018773387 cites W2078123974 @default.
- W2018773387 cites W2079511906 @default.
- W2018773387 cites W2084084886 @default.
- W2018773387 cites W2108142658 @default.
- W2018773387 cites W2143880554 @default.
- W2018773387 cites W2144107326 @default.
- W2018773387 doi "https://doi.org/10.1016/j.ijhydene.2012.02.087" @default.
- W2018773387 hasPublicationYear "2012" @default.
- W2018773387 type Work @default.
- W2018773387 sameAs 2018773387 @default.
- W2018773387 citedByCount "48" @default.
- W2018773387 countsByYear W20187733872013 @default.
- W2018773387 countsByYear W20187733872014 @default.
- W2018773387 countsByYear W20187733872015 @default.
- W2018773387 countsByYear W20187733872016 @default.
- W2018773387 countsByYear W20187733872017 @default.
- W2018773387 countsByYear W20187733872018 @default.
- W2018773387 countsByYear W20187733872019 @default.
- W2018773387 countsByYear W20187733872020 @default.
- W2018773387 countsByYear W20187733872022 @default.
- W2018773387 countsByYear W20187733872023 @default.
- W2018773387 crossrefType "journal-article" @default.
- W2018773387 hasAuthorship W2018773387A5053867045 @default.
- W2018773387 hasAuthorship W2018773387A5056679099 @default.
- W2018773387 hasConcept C119889771 @default.
- W2018773387 hasConcept C144024400 @default.
- W2018773387 hasConcept C149923435 @default.
- W2018773387 hasConcept C150394285 @default.
- W2018773387 hasConcept C161790260 @default.
- W2018773387 hasConcept C175583648 @default.
- W2018773387 hasConcept C178790620 @default.
- W2018773387 hasConcept C179104552 @default.
- W2018773387 hasConcept C185592680 @default.
- W2018773387 hasConcept C202189072 @default.
- W2018773387 hasConcept C2777595113 @default.
- W2018773387 hasConcept C2780161600 @default.
- W2018773387 hasConcept C2780178953 @default.
- W2018773387 hasConcept C2908647359 @default.
- W2018773387 hasConcept C43535742 @default.
- W2018773387 hasConcept C512968161 @default.
- W2018773387 hasConcept C518104683 @default.
- W2018773387 hasConcept C66114498 @default.
- W2018773387 hasConceptScore W2018773387C119889771 @default.
- W2018773387 hasConceptScore W2018773387C144024400 @default.
- W2018773387 hasConceptScore W2018773387C149923435 @default.
- W2018773387 hasConceptScore W2018773387C150394285 @default.
- W2018773387 hasConceptScore W2018773387C161790260 @default.
- W2018773387 hasConceptScore W2018773387C175583648 @default.
- W2018773387 hasConceptScore W2018773387C178790620 @default.